Phase Diagram Study of the Nd2O3-SiO2-FeO-Fe2O3 System at 1773 K in Air

Wenjie Wei, Shu Li, Zemeng Weng, Boya Zhang, Zhanmin Cao
{"title":"Phase Diagram Study of the Nd2O3-SiO2-FeO-Fe2O3 System at 1773 K in Air","authors":"Wenjie Wei, Shu Li, Zemeng Weng, Boya Zhang, Zhanmin Cao","doi":"10.1007/s11663-024-03189-w","DOIUrl":null,"url":null,"abstract":"<p>The phase diagram information of the Nd<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub>-FeO-Fe<sub>2</sub>O<sub>3</sub> system is basic for the design and development of slag for recycling NdFeB magnets by pyrometallurgical processes. The equilibria phase relations of the Nd<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub>-FeO-Fe<sub>2</sub>O<sub>3</sub> system were investigated at 1773 K in air using a high-temperature isothermal equilibration technique followed by quenching. Seven two-phase equilibria regions and seven three-phase equilibria regions were observed by X-ray diffraction (XRD) and scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS) analysis of quenched samples. Ternary compounds Nd<sub>9.33</sub>Si<sub>6−<i>x</i></sub>Fe<sub><i>x</i></sub>O<sub>26-δ</sub> and Nd<sub>0.67</sub>Si<sub>0.13</sub>Fe<sub>0.2</sub>O<sub>δ</sub> were found. The 1773 K isothermal section was constructed for the Nd<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub>-FeO-Fe<sub>2</sub>O<sub>3</sub> system.</p>","PeriodicalId":18613,"journal":{"name":"Metallurgical and Materials Transactions B","volume":"63 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Metallurgical and Materials Transactions B","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1007/s11663-024-03189-w","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

Abstract

The phase diagram information of the Nd2O3-SiO2-FeO-Fe2O3 system is basic for the design and development of slag for recycling NdFeB magnets by pyrometallurgical processes. The equilibria phase relations of the Nd2O3-SiO2-FeO-Fe2O3 system were investigated at 1773 K in air using a high-temperature isothermal equilibration technique followed by quenching. Seven two-phase equilibria regions and seven three-phase equilibria regions were observed by X-ray diffraction (XRD) and scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS) analysis of quenched samples. Ternary compounds Nd9.33Si6−xFexO26-δ and Nd0.67Si0.13Fe0.2Oδ were found. The 1773 K isothermal section was constructed for the Nd2O3-SiO2-FeO-Fe2O3 system.

Abstract Image

空气中 1773 K 温度下的 Nd2O3-SiO2-FeO-Fe2O3 系统相图研究
Nd2O3-SiO2-FeO-Fe2O3 体系的相图信息是设计和开发通过高温冶金工艺回收钕铁硼磁体的熔渣的基础。采用高温等温平衡技术,在 1773 K 的空气中研究了 Nd2O3-SiO2-FeO-Fe2O3 体系的平衡相关系,然后进行了淬火。通过对淬火样品进行 X 射线衍射(XRD)和扫描电子显微镜与能量色散光谱(SEM-EDS)分析,观察到七个两相平衡区和七个三相平衡区。发现了三元化合物 Nd9.33Si6-xFexO26-δ 和 Nd0.67Si0.13Fe0.2Oδ。为 Nd2O3-SiO2-FeO-Fe2O3 系统构建了 1773 K 等温截面。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信