Geochemical characteristics, genetic types, and sources of gas accumulations in the northern Jizhong subbasin, Bohai Bay Basin, eastern China

IF 4.6 Q2 MATERIALS SCIENCE, BIOMATERIALS
Nian Liu, Nansheng Qiu, Mingkuan Qin, Zhenming Li, Chuan Cai, Yuanjie Wang, Qiang Guo, Man Lu
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Abstract

Gas source and genetic type identification are important for gas system analysis and successful exploration. However, such crucial information is generally lacking or highly controversial in the northern Jizhong subbasin, Bohai Bay Basin, hindering further gas exploration. In this study, multiple genetic types of gases are identified in the northern Jizhong subbasin, including biogenic gas, coal-derived gas, and oil-associated gas. In particular, gases in the shallow Paleogene reservoirs are composed mainly of oil-associated gases derived from sapropelic organic matter in the Paleogene third member of the Shahejie Formation (Es3) and dark shales in the fourth member of the Shahejie and Kongdian Formations (Es4 + Ek). Gases in the deeply buried Ordovician and Carboniferous–Permian reservoirs are mainly derived from coal, with some contributions from oil-associated gases. The deep gases are mainly derived from the Carboniferous–Permian coal-bearing humic source rocks, with contributions from mixed organic matter in the Es4 + Ek source rocks. Biogenic gases, mainly present in the Paleogene Es3 reservoirs, are dominated by secondary microbially generated gas via CO2 reduction. Microbially generated gases are probably derived from sapropelic organic matter in the Es3 source rock. Based on the findings, it is concluded that shallow Paleogene rocks may be a favorable reservoir zone for primary (kerogen) cracking gases generated from type II1 kerogen. Dry gases derived from type III kerogen and secondary cracking gases from type II1 kerogen in the deep and ultradeep Ordovician and Precambrian–Cambrian reservoirs can be other potential exploration targets in the northern Jizhong subbasin.
中国东部渤海湾盆地冀中北亚盆地天然气聚集的地球化学特征、成因类型和来源
气源和成因类型鉴定对于天然气系统分析和成功勘探非常重要。然而,在渤海湾盆地冀中北亚盆地,这些关键信息普遍缺乏或极具争议,阻碍了进一步的天然气勘探。本研究确定了冀中北亚盆地的多种气体成因类型,包括生物气、煤源气和石油伴生气。其中,浅层古近系储层中的气体主要由古近系沙河街地层第三系(Es3)中的皂质有机质和沙河街、孔店地层第四系(Es4+Ek)中的暗色页岩衍生的油伴生气组成。深埋奥陶系和石炭系-二叠系储层中的气体主要来自煤炭,部分来自石油伴生气。深层气体主要来自石炭纪-二叠纪含煤腐殖质源岩,Es4 + Ek 源岩中的混合有机物也有贡献。生物源气体主要存在于古近纪 Es3 储层中,主要是微生物通过二氧化碳还原作用产生的二次气体。微生物产生的气体可能来自Es3源岩中的溶胶有机物。根据研究结果,可以得出结论:浅古元古代岩石可能是 II1 型角质岩产生的原生(角质)裂解气的有利储集带。深奥陶系和超深奥陶系及前寒武-寒武系储层中的Ⅲ型角质产生的干气和Ⅱ1型角质产生的二次裂解气可能是冀中北亚盆地的其他潜在勘探目标。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
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