Variations in orientation relationships between rutile inclusions and garnet host relate to magmatic growth zoning

IF 3.5 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS
Victoria Kohn, Thomas A. Griffiths, Taisia Alifirova, Nina Daneu, Olga Ageeva, Rainer Abart, Gerlinde Habler
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Abstract

Rutile inclusions in almandine-spessartine garnet from a peraluminous pegmatoid from the Moldanubian zone (Bohemian Massif, AT) show distinct changes in aspect ratio, shape preferred orientations (SPO) and crystallographic orientation relationships (COR) along the transition between microstructurally different growth zones in the garnet core and rim. For identification of the COR characteristics we pool specific CORs based on their common axial relationship into three COR groups: Group 103R/111G, Group 001R/111G and Group 001R/100G. The rutile inclusions in the garnet core domains are elongated along the four Grt\(\langle\)111\(\rangle\) directions and are dominated by COR Group 103R/111G. The garnet rim zone additionally contains rutile needles elongated along Grt\(\langle\)100\(\rangle\). Here, Group 001R/111G and 001R/100G are more abundant than in the garnet core. Needle-shaped rutile in the rim shows a systematic correlation between SPOs and CORs as needles elongated parallel to Grt\(\langle\)111\(\rangle\) are dominated by Group 103R/111G and 001R/111G, whereas those needles elongated parallel to Grt\(\langle\)100\(\rangle\) exclusively pertain to CORs of 001R/100G. Furthermore, the frequency of each particular SPO in the garnet rim clearly depends on the local growth direction of the particular Grt{112} sector. Facet-specific variations in rutile SPO frequencies in different sectors and growth zones of garnet were observed even between equivalent directions, indicating that the microstructures and textures of rutile inclusions reflect varying parameters of garnet growth. The characteristic differences in COR groups of different garnet growth zones are referred to compositional changes in the bulk melt or compositional boundary layer, associated with magmatic fractional crystallisation.

Abstract Image

金红石包裹体与石榴石主岩之间的取向关系变化与岩浆生长分带有关。
来自摩尔多瓦地区(波希米亚山丘,AT)过铝辉石石榴石中金红石包裹体的长宽比、形状优选取向(SPO)和晶体取向关系(COR)随着石榴石核心和边缘微结构不同生长区之间的过渡而发生明显变化。为了识别 COR 特性,我们根据共同的轴向关系将特定的 COR 分成三个 COR 组:103R/111G组、001R/111G组和001R/100G组。石榴石核域中的金红石包裹体沿四个 Grt ⟨ 111 ⟩ 方向拉长,以 COR 103R/111G 组为主。石榴石边缘区还含有沿 Grt ⟨ 100 ⟩ 方向拉长的金红石针。在这里,001R/111G 组和 001R/100G 组的含量高于石榴石核心区。边缘中的针状金红石显示出 SPOs 和 CORs 之间的系统相关性,因为平行于 Grt ⟨ 111 ⟩ 的针状金红石以 103R/111G 和 001R/111G 组为主,而平行于 Grt ⟨ 100 ⟩ 的针状金红石则完全与 001R/100G 的 CORs 有关。此外,石榴石边缘中每个特定 SPO 的频率显然取决于特定 Grt{112} 扇形的局部生长方向。在石榴石的不同扇形和生长区中,甚至在等效方向之间也观察到了金红石 SPO 频率的特定面变化,这表明金红石夹杂物的微观结构和纹理反映了石榴石生长的不同参数。不同石榴石生长区 COR 组的特征性差异是由于块体熔体或成分边界层中的成分变化造成的,与岩浆分段结晶有关:在线版本包含补充材料,可查阅 10.1007/s00410-024-02146-9。
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来源期刊
Contributions to Mineralogy and Petrology
Contributions to Mineralogy and Petrology 地学-地球化学与地球物理
CiteScore
6.50
自引率
5.70%
发文量
94
审稿时长
1.7 months
期刊介绍: Contributions to Mineralogy and Petrology is an international journal that accepts high quality research papers in the fields of igneous and metamorphic petrology, geochemistry and mineralogy. Topics of interest include: major element, trace element and isotope geochemistry, geochronology, experimental petrology, igneous and metamorphic petrology, mineralogy, major and trace element mineral chemistry and thermodynamic modeling of petrologic and geochemical processes.
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