Introducing Ce ions and oxygen vacancies into VO2 nanostructures with high specific surface area for efficient aqueous Zn-ion storage

ChemPhysMater Pub Date : 2025-01-01 DOI:10.1016/j.chphma.2024.05.004

Mingying Bao , Zhengchunyu Zhang , Xuguang An , Baojuan Xi , Shenglin Xiong

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Abstract

Positive electrodes play a decisive role in exploring the Zn²⁺ storage mechanism and improving the electrochemical performance of aqueous Zn-ion batteries (AZIBs). Feasible design and preparation of cathode materials have been crucial for AZIBs in recent years. Herein, taking the advantage of the tunnel structure of VO₂, which can withstand volume change during charging/discharging, VO₂ doped with Ce ions is synthesized by a simple one-step hydrothermal method and oxygen vacancies are synchronously generated during synthesis. It delivers a capacity of 158.5 mAh g⁻¹ at the current density of 5 A g⁻¹ after 1000 cycles and exhibits an excellent energy density of 312.8 Wh kg⁻¹ at the power density of 142 W kg⁻¹. The structural modification and prospect of enhancing its conductivity by doping with rare-earth metals and introducing oxygen vacancies may aid in improving the stability of AZIBs in the future.

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在具有高比表面积的 VO2 纳米结构中引入 Ce 离子和 O2 缺陷，实现 Zn 离子的高效水溶液储存

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