Hot Exciton versus Hot Exciplex TADF Mechanism – Effect of the Donor-Acceptor Functionalization Pattern on Anthracene-based Emitters

IF 3 4区 化学 Q3 CHEMISTRY, PHYSICAL
Felix Majer, Lars Roß, A. Lennart Respondek, Christoph Bannwarth, Alexander J. C. Kuehne
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引用次数: 0

Abstract

Hot exciton emitters based on 9,10-substituted anthracenes are a well-investigated class of molecules featuring thermally activated delayed fluorescence (TADF). TADF converts triplet excitons into singlet excitons and improves the internal quantum efficiency of electroluminescent devices to performance beyond the limit of spin-statistics of conventional emitters. In this paper, we compare different 1,8-functionalized donor/acceptor-substituted anthracenes and compare these to established 9,10-functionalized hot exciton emitters. Interestingly, our new 1,8-substituted anthracenes make use of a beneficial hot exciplex pathway, resulting in improved emission characteristics and higher photoluminescence quantum yield.

Abstract Image

热激子与热激簇 TADF 机制--蒽基发光体上的供体-受体功能化模式的影响
基于 9,10-取代蒽的热激子发光体是一类经过深入研究的分子,其特点是热激活延迟荧光(TADF)。TADF 可将三重激子转化为单重激子,从而提高电致发光器件的内部量子效率,使其性能超越传统发射器的自旋统计极限。在本文中,我们比较了不同的 1,8 功能化供体/受体取代蒽,并将其与已有的 9,10 功能化热激子发光体进行了比较。有趣的是,我们的新型 1,8 取代蒽利用了有益的热激子途径,从而改善了发射特性并提高了光量子产率。
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来源期刊
ChemPhotoChem
ChemPhotoChem Chemistry-Physical and Theoretical Chemistry
CiteScore
5.80
自引率
5.40%
发文量
165
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