A Zn(II)-based 1D Coordination Polymer with Adsorption Properties and Hirshfeld Surface Analysis

IF 2.1 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY
Safarov Azamat Rasulovich, Ibragimov Aziz Bakhtiyarovich, Ruzmetov Abror Khamidjanovich, Normamatov Adkhamjon Sadullayevich, Yakubov Yuldosh Yusupboyevich, Abdullaev Ahrorjon Khabibjonovich, Adizov Bobirjon Zamirovich, Eshmetov Izzat Dosimbatovich, Muhammad Nadeem Akhtar, Ibragimov Avazbek Bakhtiyarovich, Ashurov Jamshid Mengnorovich
{"title":"A Zn(II)-based 1D Coordination Polymer with Adsorption Properties and Hirshfeld Surface Analysis","authors":"Safarov Azamat Rasulovich,&nbsp;Ibragimov Aziz Bakhtiyarovich,&nbsp;Ruzmetov Abror Khamidjanovich,&nbsp;Normamatov Adkhamjon Sadullayevich,&nbsp;Yakubov Yuldosh Yusupboyevich,&nbsp;Abdullaev Ahrorjon Khabibjonovich,&nbsp;Adizov Bobirjon Zamirovich,&nbsp;Eshmetov Izzat Dosimbatovich,&nbsp;Muhammad Nadeem Akhtar,&nbsp;Ibragimov Avazbek Bakhtiyarovich,&nbsp;Ashurov Jamshid Mengnorovich","doi":"10.1007/s11224-024-02340-2","DOIUrl":null,"url":null,"abstract":"<div><p>A polymeric coordination compound [Zn<sub>2(</sub>PABA)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>Cl<sub>2</sub>]<sub>n</sub> (<b>1</b>) (where PABA is para-aminobenzoic acid) has been synthesized and characterized. We examined and explicated the porosity of the compound and employed a low-temperature nitrogen adsorption technique at 77 kelvins. Throughout the experiments, the nitrogen partial pressure ranged from 0.005 to 0.995 P/P<sup>0</sup>, aligning with the nitrogen adsorption and desorption curves. The surface area (SBET) was found to be 1945.72 m<sup>2</sup>/g with a micropore area of 361.56 m<sup>2</sup>/g that ensures the material’s ability to effectively adsorb small molecules. The nitrogen adsorption behavior on this compound is not only facilitates a deeper comprehension of its textural and structural attributes but also unveils potential applications, especially in pharmaceutical domains. Additionally, Hirschfeld surface analysis was performed, yielding interatomic interaction percentages on the Hirschfeld surface.</p></div>","PeriodicalId":780,"journal":{"name":"Structural Chemistry","volume":"35 6","pages":"2021 - 2031"},"PeriodicalIF":2.1000,"publicationDate":"2024-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Structural Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11224-024-02340-2","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

A polymeric coordination compound [Zn2(PABA)2(H2O)2Cl2]n (1) (where PABA is para-aminobenzoic acid) has been synthesized and characterized. We examined and explicated the porosity of the compound and employed a low-temperature nitrogen adsorption technique at 77 kelvins. Throughout the experiments, the nitrogen partial pressure ranged from 0.005 to 0.995 P/P0, aligning with the nitrogen adsorption and desorption curves. The surface area (SBET) was found to be 1945.72 m2/g with a micropore area of 361.56 m2/g that ensures the material’s ability to effectively adsorb small molecules. The nitrogen adsorption behavior on this compound is not only facilitates a deeper comprehension of its textural and structural attributes but also unveils potential applications, especially in pharmaceutical domains. Additionally, Hirschfeld surface analysis was performed, yielding interatomic interaction percentages on the Hirschfeld surface.

Abstract Image

一种具有吸附特性和 Hirshfeld 表面分析的锌(II)基一维配位聚合物
我们合成了一种聚合物配位化合物[Zn2(PABA)2(H2O)2Cl2]n (1)(其中 PABA 是对氨基苯甲酸),并对其进行了表征。我们研究并解释了该化合物的孔隙率,并在 77 开尔文条件下采用了低温氮吸附技术。在整个实验过程中,氮分压在 0.005 至 0.995 P/P0 之间,与氮吸附和解吸曲线一致。表面积(SBET)为 1945.72 m2/g,微孔面积为 361.56 m2/g,确保了材料有效吸附小分子的能力。该化合物的氮吸附行为不仅有助于深入理解其质地和结构属性,还揭示了其潜在的应用领域,尤其是在制药领域。此外,还进行了赫希菲尔德表面分析,得出了赫希菲尔德表面的原子间相互作用百分比。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Structural Chemistry
Structural Chemistry 化学-化学综合
CiteScore
3.80
自引率
11.80%
发文量
227
审稿时长
3.7 months
期刊介绍: Structural Chemistry is an international forum for the publication of peer-reviewed original research papers that cover the condensed and gaseous states of matter and involve numerous techniques for the determination of structure and energetics, their results, and the conclusions derived from these studies. The journal overcomes the unnatural separation in the current literature among the areas of structure determination, energetics, and applications, as well as builds a bridge to other chemical disciplines. Ist comprehensive coverage encompasses broad discussion of results, observation of relationships among various properties, and the description and application of structure and energy information in all domains of chemistry. We welcome the broadest range of accounts of research in structural chemistry involving the discussion of methodologies and structures,experimental, theoretical, and computational, and their combinations. We encourage discussions of structural information collected for their chemicaland biological significance.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信