Amplitude equation for a diffusion–reaction system in presence of complexing reaction with the activator species: the Brusselator model

IF 1.7 3区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY
A. K. Dutt
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引用次数: 0

Abstract

For Brusselator diffusion–reaction model involving complex forming reaction with the activator species, an amplitude equation has been derived in the framework of a weakly nonlinear theory. Complexing reaction with the activator species strongly influences the time-dependent amplitudes such as in Hopf-wave bifurcations, whereas time-independent amplitudes such as in Turing—bifurcations, are independent of complexing reaction with the activator species. Complexing reaction arrests the arrival of Hopf—bifurcations and the domain of excitable non-oscillations such created may be used effectively for Turing-structure generation by inducing inhomogeneous perturbations of nonzero wavenumber mode. Any major complexing interaction with the activator species in a biological oscillatory network is bound to alter the domains of Hopf/Turing bifurcations affecting the course of physiological self-organization processes.

Abstract Image

存在与活化剂物种的复合反应的扩散反应系统的振幅方程:布鲁塞尔模型
对于涉及与活化剂物种发生络合反应的布鲁塞尔扩散反应模型,我们在弱非线性理论框架内推导出了一个振幅方程。与活化剂物种的络合反应会强烈影响与时间相关的振幅,如霍普夫波分岔,而与时间无关的振幅,如图灵分岔,则与与活化剂物种的络合反应无关。络合反应会阻止霍普夫分岔的发生,所产生的可激发非振荡域可通过诱导非零波数模式的不均匀扰动,有效地用于图灵结构的生成。在生物振荡网络中,与激活剂物种之间的任何重大复合相互作用都必然会改变霍普夫/图灵分岔域,从而影响生理自组织过程的进程。
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来源期刊
Journal of Mathematical Chemistry
Journal of Mathematical Chemistry 化学-化学综合
CiteScore
3.70
自引率
17.60%
发文量
105
审稿时长
6 months
期刊介绍: The Journal of Mathematical Chemistry (JOMC) publishes original, chemically important mathematical results which use non-routine mathematical methodologies often unfamiliar to the usual audience of mainstream experimental and theoretical chemistry journals. Furthermore JOMC publishes papers on novel applications of more familiar mathematical techniques and analyses of chemical problems which indicate the need for new mathematical approaches. Mathematical chemistry is a truly interdisciplinary subject, a field of rapidly growing importance. As chemistry becomes more and more amenable to mathematically rigorous study, it is likely that chemistry will also become an alert and demanding consumer of new mathematical results. The level of complexity of chemical problems is often very high, and modeling molecular behaviour and chemical reactions does require new mathematical approaches. Chemistry is witnessing an important shift in emphasis: simplistic models are no longer satisfactory, and more detailed mathematical understanding of complex chemical properties and phenomena are required. From theoretical chemistry and quantum chemistry to applied fields such as molecular modeling, drug design, molecular engineering, and the development of supramolecular structures, mathematical chemistry is an important discipline providing both explanations and predictions. JOMC has an important role in advancing chemistry to an era of detailed understanding of molecules and reactions.
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