Formation of Structural-Phase State and Elastic and Durometric Properties of Biocompatible Cold-Rolled Titanium Ti–Nb–Zr-Based Alloys during Aging

IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING
A. A. Korenev, A. G. Illarionov, M. S. Karabanalov
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引用次数: 0

Abstract—The methods of scanning electron microscopy, X-ray diffraction analysis, and microindentation are used to study the effect of alloying with zirconium (within 3 to 6 at %) and complex Zr + Sn and Zr + Sn + Ta additions on the evolution of the structure, phase composition, and properties (effective modulus of elasticity, hardness, and wear-resistance parameters) of quenched biocompatible β-titanium (at %) Ti–26% Nb–3% Zr, Ti–26% Nb–5% Zr, Ti–26% Nb–6% Zr, Ti–26% Nb–3% Zr–1% Sn, and Ti–26% Nb–3% Zr–1% Sn–0.7Ta alloys during aging (at 400°C for 4, 16, and 64 h) after multipass cold rolling with a total degree of strain of 85%. As compared to the quenching, the cold rolling of the studied Ti–Nb–Zr alloys is shown to suppress the occurrence of the β → ω transformation in the course of aging and to favor the acceleration of the decomposition of β solid solution with the formation of nonequilibrium αl phase in the course of aging. The increase in the zirconium content from 3 to 6 at % in the cold-rolled ternary Ti–26% Nb – х% Zr alloys and introduction of complex Zr + Sn and Zr + Sn + Ta additions to the Ti–26% Nb alloy instead of only zirconium addition hinder the decomposition processes of the β phase during aging; this impacts the intensity of variations of the effective modulus of elasticity and microhardness. The aging of the cold-rolled alloys under study was found to allows us to obtain the higher values of the parameters H/Er and \({{{{H}^{3}}} \mathord{\left/ {\vphantom {{{{H}^{3}}} {E_{{\text{r}}}^{2}}}} \right. \kern-0em} {E_{{\text{r}}}^{2}}}\) (Н is the hardness and Er is the resolved modulus of elasticity) associated with the wear resistance as compared to those for the widely used medical Ti–6Al–4V alloy. The compositions of the alloys and conditions of their treatment are determined, which allow us to obtain the combination of the highest-level properties.

Abstract Image

生物相容性冷轧钛 Ti-Nb-Zr 基合金在老化过程中形成的结构相态以及弹性和耐久性能
摘要 采用扫描电子显微镜、X 射线衍射分析和显微压痕等方法研究了锆合金(3% 至 6%)和 Zr + Sn 及 Zr + Sn + Ta 复合添加物对淬火生物相容性 β-钛(Ti-26% Nb-3% Ti-26%Nb-3%Zr)结构、相组成和性能(有效弹性模量、硬度和耐磨性参数)演变的影响、和性能(有效弹性模量、硬度和耐磨性参数)的变化。7Ta 合金在总应变度为 85% 的多道次冷轧后的老化过程(400°C,4、16 和 64 小时)中的变化。与淬火相比,所研究的 Ti-Nb-Zr 合金的冷轧可抑制时效过程中发生的 β → ω 转变,并有利于加速 β 固溶体的分解,在时效过程中形成非平衡的 αl 相。将冷轧三元 Ti-26% Nb - х% Zr 合金中的锆含量从 3% 提高到 6%,以及在 Ti-26% Nb 合金中引入复合 Zr + Sn 和 Zr + Sn + Ta 添加剂(而不是仅添加锆),都阻碍了β相在时效过程中的分解过程;这影响了有效弹性模量和显微硬度的变化强度。研究发现,冷轧合金的时效可以使我们获得更高的参数值 H/Er 和 \({{{{H}^{3}}} 。\mathord\{left/ {\vphantom {{{{H}^{3}}}{E_{{\text{r}}}^{2}}}}\right.\kern-0em}}{E_{{text{r}}^{2}}})(Н为硬度,Er为解析弹性模量)与广泛使用的医用 Ti-6Al-4V 合金的耐磨性相关。通过确定合金的成分及其处理条件,我们可以获得最高级别的性能组合。
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来源期刊
Physics of Metals and Metallography
Physics of Metals and Metallography 工程技术-冶金工程
CiteScore
2.00
自引率
25.00%
发文量
108
审稿时长
3 months
期刊介绍: The Physics of Metals and Metallography (Fizika metallov i metallovedenie) was founded in 1955 by the USSR Academy of Sciences. Its scientific profile involves the theory of metals and metal alloys, their electrical and magnetic properties, as well as their structure, phase transformations, and principal mechanical properties. The journal also publishes scientific reviews and papers written by experts involved in fundamental, application, and technological studies. The annual volume of publications amounts to some 250 papers submitted from 100 leading national scientific institutions.
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