Photovoltaic Cell Prepared from Nanoparticles of CdS/CdTe on ITO Substrate and its Characterization

Aditi Priyadarshini, Kumar Nikhil, K. P. Tiwary
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Abstract

CdS/CdTe based photovoltaic cell has shown the markable efficiency. The CdS/CdTe nanoparticles are being synthesized and deposited on the ITO glass plate. ITO glass has a large bandgap of about approximately 3.6 eV and is suitable to use in the fabrication of photovoltaic cell. As ITO behaves as negative terminal, it is used as front layer for capturing the light intensity. During fabrication of photovoltaic cell, the deposition of Cadmium sulphide and Cadmium telluride nanoparticles layer was done by brush painting technique. The CdS layer is used as window layer and CdTe acts as absorbing layer. The window layer’s primary function is to absorb light particularly in the visible region of the spectrum to generate electricity. The CdS layer forms p-n junction with the CdTe layer. The nanoparticles of CdS and CdTe have been synthesized first and optical characterization was carried out using UV-visible spectroscopy to obtain bandgap of CdTe and CdS. Structural characterization was being obtained by XRD. The size of the nanocrystallites of CdS and CdTe have been obtained by Debye Scherrer equation and the result was 1.64 nm and 4.09 nm respectively. The CdTe layer which was used as absorbing layer consists of high optical absorption coefficient with high mobility, good carrier lifetime and an enhanced properties of crystallographic. Silver paste was used as a back contact for good conduction.
在 ITO 基底上利用 CdS/CdTe 纳米粒子制备光伏电池及其特性分析
基于 CdS/CdTe 的光伏电池具有显著的效率。CdS/CdTe 纳米粒子被合成并沉积在 ITO 玻璃板上。ITO 玻璃具有约 3.6 eV 的大带隙,适合用于制造光伏电池。由于 ITO 表现为负极,因此可用作捕捉光强的前层。在制造光伏电池的过程中,硫化镉和碲化镉纳米粒子层的沉积是通过刷涂技术完成的。硫化镉层用作窗口层,碲化镉层用作吸收层。窗口层的主要功能是吸收光线,尤其是光谱中可见区域的光线,从而产生电能。CdS 层与 CdTe 层形成 p-n 结。首先合成了 CdS 和 CdTe 纳米粒子,然后使用紫外可见光谱进行了光学表征,以获得 CdTe 和 CdS 的带隙。通过 XRD 获得了结构特征。CdS 和 CdTe 纳米晶体的尺寸是通过德拜-舍勒方程求得的,结果分别为 1.64 nm 和 4.09 nm。用作吸收层的碲化镉层具有高光学吸收系数、高迁移率、良好的载流子寿命和更强的晶体学特性。银浆被用作背触点,以实现良好的传导。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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