Positive steady states of a class of power law systems with independent decompositions

IF 1.7 3区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY
Al Jay Lan J. Alamin, Bryan S. Hernandez
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Abstract

Power law systems have been studied extensively due to their wide-ranging applications, particularly in chemistry. In this work, we focus on power law systems that can be decomposed into stoichiometrically independent subsystems. We show that for such systems where the ranks of the augmented matrices containing the kinetic order vectors of the underlying subnetworks sum up to the rank of the augmented matrix containing the kinetic order vectors of the entire network, then the existence of the positive steady states of each stoichiometrically independent subsystem is a necessary and sufficient condition for the existence of the positive steady states of the given power law system. We demonstrate the result through illustrative examples. One of which is a network of a carbon cycle model that satisfies the assumptions, while the other network fails to meet the assumptions. Finally, using the aforementioned result, we present a systematic method for deriving positive steady state parametrizations for the mentioned subclass of power law systems, which is a generalization of our recent method for mass action systems.

Abstract Image

一类具有独立分解的幂律系统的正稳态
由于幂律系统的广泛应用,尤其是在化学领域的应用,人们对它进行了广泛的研究。在这项研究中,我们重点研究了可分解为独立于化学计量学的子系统的幂律系统。我们的研究表明,对于这类系统,如果包含底层子网络动能阶次向量的增强矩阵的阶次总和等于包含整个网络动能阶次向量的增强矩阵的阶次,那么每个化学计量学独立子系统正稳态的存在就是给定幂律系统正稳态存在的必要条件和充分条件。我们通过示例来证明这一结果。其中一个碳循环模型网络满足假设条件,而另一个网络则不满足假设条件。最后,利用上述结果,我们提出了一种为上述幂律系统子类推导正稳态参数的系统方法,它是我们最近对质量作用系统方法的推广。
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来源期刊
Journal of Mathematical Chemistry
Journal of Mathematical Chemistry 化学-化学综合
CiteScore
3.70
自引率
17.60%
发文量
105
审稿时长
6 months
期刊介绍: The Journal of Mathematical Chemistry (JOMC) publishes original, chemically important mathematical results which use non-routine mathematical methodologies often unfamiliar to the usual audience of mainstream experimental and theoretical chemistry journals. Furthermore JOMC publishes papers on novel applications of more familiar mathematical techniques and analyses of chemical problems which indicate the need for new mathematical approaches. Mathematical chemistry is a truly interdisciplinary subject, a field of rapidly growing importance. As chemistry becomes more and more amenable to mathematically rigorous study, it is likely that chemistry will also become an alert and demanding consumer of new mathematical results. The level of complexity of chemical problems is often very high, and modeling molecular behaviour and chemical reactions does require new mathematical approaches. Chemistry is witnessing an important shift in emphasis: simplistic models are no longer satisfactory, and more detailed mathematical understanding of complex chemical properties and phenomena are required. From theoretical chemistry and quantum chemistry to applied fields such as molecular modeling, drug design, molecular engineering, and the development of supramolecular structures, mathematical chemistry is an important discipline providing both explanations and predictions. JOMC has an important role in advancing chemistry to an era of detailed understanding of molecules and reactions.
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