Selektivitas Adsorpsi Campuran Biner Fe(II)/Cu(II) Menggunakan Karbon Aktif dari Sekam Padi dan Serbuk Gergaji Kayu Jati

Abstract

Increasing human needs cause an increase in production on an industrial scale and can have an impact on increasing contamination of the aquatic environment. Efforts to improve water quality can be made by removing contaminants using renewable activated carbon originating from agricultural waste such as rice husks and teak sawdust. This research aims to examine the adsorption capacity of activated carbon from rice husks (RHAC) and teak sawdust (TSAC) on a binary mixture of Fe(II)/Cu(II) as well as the level of selectivity of each adsorbent on Fe(II) and Cu(II) ions. RHAC and TSAC activated carbon are produced through carbonization processes (T=400 °C, t=60 minutes), reflux (NaOH 2N, T=100 °C, t=120 minutes), chemical activation using H3PO4 (30%, 1:3, b/b) and physics (furnace). The results of this research are that RHAC and TSAC activated carbon have the functional groups O-H (str), C-H (str), C≡C, C=C, C-O (str), and C-O-P (str). The surface character of RHAC and TSAC activated carbon is dominated by the elements C, O, and P. The results of the Fe(II) and Cu(II) ion adsorption treatment using RHAC and TSAC activated carbon follow PSO kinetic modeling with R2 values of 0.9221 and 0.9565 on RHAC and 0.9915 and 0.97 on TSAC. TSAC-activated carbon more selectively adsorbs Fe(II) and Cu(II) ions compared to RHAC-activated carbon with adsorption percentages reaching 97.34% and 87.82%, respectively.