Tailoring structure, morphology, and tribo-mechanical properties of HiPIMS-deposited CrxNy coatings for enhanced performance in wear and corrosion protection

Nassima Jaghar, Mohamed Lahouij, H. Larhlimi, O. Abegunde, Y. Samih, M. Makha, J. Alami
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Abstract

During reactive sputtering of CrxNy, precise regulation of nitrogen gas is crucial to control the properties of the deposited coating. In the present work, we investigate the influence of nitrogen content on CrxNy characteristics, including morphology, crystalline structure, hardness, corrosion protection, and wear protection performances. Our findings reveal that the hexagonal Cr2N coatings, although slightly lower in hardness (19 GPa) compared to stoichiometric CrN, exhibit superior corrosion resistance with a protection efficiency of 82%, and a reduced sliding wear behavior at 1.35E-09 mm3/N/m. Conversely, stoichiometric CrN shows the highest hardness at 22.8 GPa. Using high-power impulsed magnetron sputtering as a deposition technique, we were able to design CrxNy protective coatings with desired microstructure and phase composition, enabling the production of performance-tailored CrxNy coatings suitable for a diverse range of applications.
调整 HiPIMS 沉积 CrxNy 涂层的结构、形貌和三力学性能,提高其磨损和腐蚀防护性能
在反应溅射 CrxNy 的过程中,氮气的精确调节对于控制沉积涂层的性能至关重要。在本研究中,我们研究了氮气含量对 CrxNy 特性的影响,包括形态、结晶结构、硬度、腐蚀保护和磨损保护性能。我们的研究结果表明,六方 Cr2N 涂层的硬度(19 GPa)虽然略低于化学合成 CrN,但却表现出卓越的耐腐蚀性能,保护效率高达 82%,滑动磨损性能也有所降低(1.35E-09 mm3/N/m)。相反,化学合成铬镍的硬度最高,为 22.8 GPa。利用高功率脉冲磁控溅射沉积技术,我们能够设计出具有所需微观结构和相组成的 CrxNy 保护涂层,从而生产出适合各种应用的性能定制 CrxNy 涂层。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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