Lead (Pb) Sorption Kinetics by Clay Minerals: Bentonite and Zeolite

Mohanapriya Ganesan, Chitdeshwari Thiyagarajan, Shanmugasundaram Rengaswamy, Maheswari Muthunalliappan, S. Alagarswamy
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Abstract

Background: Heavy metal pollution chiefly lead (Pb) causes various environmental disequilibrium and health hazards. Immobilization of lead (Pb) usingclay minerals is cost effective for metal remediation due to their higher surface area and negative charges. Methods: This study was taken up to assess the Pb removal potentials of bentonite and zeolite from contaminated water and to study the effect of sorbent dosage, initial Pb2+ concentrations and incubation time intervals on Pb adsorption and desorption was studied. Result: Zeolite was effective in immobilising Pb (78.0%) than bentonite (70.9%) which increased with increasing sorbent dosage and time intervals. The pseudo second-order kinetic model described the Pb adsorption precisely. Chemisorption was the dominant mechanism operating in aqueous solution system, hence, it could be concluded that zeolite can be utilized as an efficient sorbent for wastewater treatment.
粘土矿物对铅(Pb)的吸附动力学:膨润土和沸石
背景:以铅(Pb)为主的重金属污染会造成各种环境失衡和健康危害。利用粘土矿物固定铅(Pb)是一种经济有效的金属修复方法,因为粘土矿物具有较高的表面积和负电荷。方法:本研究旨在评估膨润土和沸石从受污染的水中去除铅的潜力,并研究吸附剂用量、初始 Pb2+ 浓度和培养时间间隔对铅吸附和解吸的影响。研究结果沸石对铅的固定效果(78.0%)优于膨润土(70.9%),随着吸附剂用量和时间间隔的增加,固定效果也随之增加。伪二阶动力学模型精确地描述了铅的吸附。化学吸附是水溶液系统中的主要运行机制,因此可以得出结论,沸石可作为一种高效的吸附剂用于废水处理。
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