Surface structural transformation and adsorption performance of Poly(triazine imide)

Abstract

Poly(triazine imide) synthesized by the molten salt route with incorporation of Li+ and Cl‒ ions (PTI/Li + Cl-) was prepared by rational controlling the washing extent. The surface transformation of the phase-pure PTI framework incurred by thorough washing has been confirmed by a systematic analysis based on XRD, UV Raman, AFM and XPS measurements. Uranyl ion adsorption experiments further support the surface structural transformation from triazine-unit PTI to heptazine-based graphitic carbon nitride. Efforts on the exploration of PTI material application should be mainly directed to the waterless fields to give good repeatability.