M. Palumbo, E. M. Dematteis, L. Fenocchio, G. Cacciamani, M. Baricco
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引用次数: 0
Abstract
Hydrides enable handling hydrogen at low pressure and near room temperature, offering higher volumetric densities than compressed or liquid hydrogen and enhancing safety. The CALPHAD method, rooted in the principles of thermodynamics, offers a systematic approach for predicting phase equilibria and thermodynamic properties in multicomponent materials. This comprehensive review paper aims to provide a detailed overview of the application of the CALPHAD method in the realm of metallic and complex hydrides. After an introduction to the fundamental thermodynamic aspects of hydrides, key elements of applying the CALPHAD method to model metal-hydrogen systems and complex hydrides are discussed. Subsequently, recent publications are reviewed, highlighting key findings and recent progresses in the field. Finally, the challenges that must be overcome to achieve further progress in this area are explored.
期刊介绍：
The most trusted journal for phase equilibria and thermodynamic research, ASM International''s Journal of Phase Equilibria and Diffusion features critical phase diagram evaluations on scientifically and industrially important alloy systems, authored by international experts.
The Journal of Phase Equilibria and Diffusion is critically reviewed and contains basic and applied research results, a survey of current literature and other pertinent articles. The journal covers the significance of diagrams as well as new research techniques, equipment, data evaluation, nomenclature, presentation and other aspects of phase diagram preparation and use.
Content includes information on phenomena such as kinetic control of equilibrium, coherency effects, impurity effects, and thermodynamic and crystallographic characteristics. The journal updates systems previously published in the Bulletin of Alloy Phase Diagrams as new data are discovered.
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