Polygeneration (Power, Water, Hydrogen and Heat) by a Novel Cycle Based on Solid Oxide Fuel Cell Integrated with Micro-Gas Turbine, Metal Hydride, and Desalination

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Masood Ebrahimi, Mohammad Aryanfar
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Abstract

In the present research, a novel cycle for simultaneous, distributed, micro-scale production of electricity, water, and hydrogen is proposed based on solid oxide fuel cell (SOFC), micro-gas turbine (MGT), thermal vapor compression single-effect desalination (TVC-SED), and metal hydride (MH). The exhaust of the SOFC is first used in an external steam reformer; then, it turns an MGT and finally produces steam for a TVC-SED unit. Excess hydrogen is stored in a metal hydride. The cycle is modeled thermodynamically and then coded in the Engineering Equation Solver. The models of the SOFC and TVC-SED are validated. The parametric analyses show that the TVC-SED performance is most sensitive to the boiling temperature and compression ratio of ejector and least sensitive to the seawater salinity, motive steam pressure and seawater temperature. The SOFC and the MGT are most sensitive to the reformer temperature. The cycle is applied to a case study in the warm climate in Iran and revealed that the cycle produces the electricity demand of a five-family residential building and water demand of 32 people. The performance ratio of TVC-SED, electrical and overall efficiencies is 1.55, 65.01 and 72.99%. The cycle stores 623.7 kg of hydrogen and sells 1.32 MW of electricity annually.

Abstract Image

通过基于固体氧化物燃料电池与微型燃气轮机、金属氢化物和海水淡化相结合的新型循环实现多联产(发电、供水、制氢和供热
本研究基于固体氧化物燃料电池 (SOFC)、微型燃气轮机 (MGT)、热蒸汽压缩单效脱盐 (TVC-SED) 和金属氢化物 (MH) 提出了一种新型循环,用于同时、分布式、微型生产电、水和氢。SOFC 排出的废气首先用于外部蒸汽转化器,然后转化为 MGT,最后为 TVC-SED 装置产生蒸汽。多余的氢储存在金属氢化物中。该循环采用热力学模型,然后在工程方程求解器中进行编码。SOFC 和 TVC-SED 的模型已通过验证。参数分析表明,TVC-SED 的性能对沸腾温度和喷射器压缩比最为敏感,而对海水盐度、动力蒸汽压力和海水温度的敏感性最低。SOFC 和 MGT 对重整器温度最为敏感。该循环应用于伊朗温暖气候条件下的案例研究,结果表明,该循环可满足一栋五户住宅楼的用电需求和 32 人的用水需求。TVC-SED 的性能比、电效率和总效率分别为 1.55%、65.01% 和 72.99%。该循环每年可储存 623.7 千克氢气,销售 1.32 兆瓦电力。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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