Bismuth Triflate Catalyzed Intermolecular Cyclization of Thiophenols with Allylic Alcohols

IF 1.7 4区化学 Q3 CHEMISTRY, ORGANIC

Synlett Pub Date : 2024-05-06 DOI:10.1055/a-2312-0631

Maki Minakawa, Taichi Inaba, Shoki Oikawa

引用次数: 0

Abstract

The catalytic intermolecular cyclization of thiophenols with allylic alcohols in the presence of bismuth triflate afforded the corresponding thiochromane derivatives in a one-pot reaction. The Bi(OTf)₃-catalyzed reaction was also applied to the intermolecular cyclization of diaryl disulfides with 3-methylbut-2-en-1-ol to produce the corresponding thiochromanes.

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三氟化铋催化噻吩醇与烯丙基醇的分子间环化反应

在三酸铋存在下，噻吩酚与烯丙基醇的分子间环化催化反应可在一锅反应中生成相应的硫代苯并吡喃衍生物。Bi(OTf)3 催化的反应还应用于二芳基二硫化物与 3-甲基丁-2-烯-1-醇的分子间环化反应，生成相应的硫代色烷。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Synlett 化学-有机化学

CiteScore

3.40

自引率

5.00%

发文量

369

审稿时长

1 months

期刊介绍： SYNLETT is an international journal reporting research results and current trends in chemical synthesis in short personalized reviews and preliminary communications. It covers all fields of scientific endeavor that involve organic synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines and offers the possibility to publish scientific primary data.