Native Cobalt in Deep Levels of the Kola Superdeep Borehole

IF 0.8 4区 地球科学 Q3 GEOLOGY
T. A. Gornostaeva, A. V. Mokhov, P. M. Kartashov, K. V. Lobanov
{"title":"Native Cobalt in Deep Levels of the Kola Superdeep Borehole","authors":"T. A. Gornostaeva, A. V. Mokhov, P. M. Kartashov, K. V. Lobanov","doi":"10.1134/s107570152308007x","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>Native cobalt was found in amphibolite of the Kola superdeep borehole (SG-3) from a depth of 9630 m by a complex of local analytical methods (analytical scanning electron microscopy, electron backscatter diffraction). The studied amphibolite is a fine-grained melanocratic rock composed mainly of magnesioferri- hornblende and containing accessory native metal, telluride, sulphotelluride, and sulphide (Au, Ag, Pd, Bi, Cu, Pb, Zn, Sb, and Fe) mineralization.It also includes the clinopyroxene xenoclast carrying a fundamentally different set of accessories—poor in sulphides and including native cobalt. The absence of significant impurities, including iron, in native cobalt and its belonging to the hexagonal α-modification was determined. It is shown, that the metallic cobalt particles exposed during ion polishing of a compact pyroxene matrix cannot be a contaminant, introduced into the sample during drilling and sample preparation. Cobalt, obviously, was formed not only before the stage of retrograde metamorphism and subsequent hydrothermal processing of the amphibolite containing it, but probably long before the formation of the sedimentary protolith of this rock. That is, native cobalt belongs to the early high-temperature mineral phases inherited from the older Proterozoic—Archean main volcanism, while the time of formation of this layer of amphibolites dates back to the age of 2.4 billion years—the Early Karelian era of the Proterozoic.</p>","PeriodicalId":12719,"journal":{"name":"Geology of Ore Deposits","volume":"17 1","pages":""},"PeriodicalIF":0.8000,"publicationDate":"2024-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Geology of Ore Deposits","FirstCategoryId":"89","ListUrlMain":"https://doi.org/10.1134/s107570152308007x","RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"GEOLOGY","Score":null,"Total":0}
引用次数: 0

Abstract

Native cobalt was found in amphibolite of the Kola superdeep borehole (SG-3) from a depth of 9630 m by a complex of local analytical methods (analytical scanning electron microscopy, electron backscatter diffraction). The studied amphibolite is a fine-grained melanocratic rock composed mainly of magnesioferri- hornblende and containing accessory native metal, telluride, sulphotelluride, and sulphide (Au, Ag, Pd, Bi, Cu, Pb, Zn, Sb, and Fe) mineralization.It also includes the clinopyroxene xenoclast carrying a fundamentally different set of accessories—poor in sulphides and including native cobalt. The absence of significant impurities, including iron, in native cobalt and its belonging to the hexagonal α-modification was determined. It is shown, that the metallic cobalt particles exposed during ion polishing of a compact pyroxene matrix cannot be a contaminant, introduced into the sample during drilling and sample preparation. Cobalt, obviously, was formed not only before the stage of retrograde metamorphism and subsequent hydrothermal processing of the amphibolite containing it, but probably long before the formation of the sedimentary protolith of this rock. That is, native cobalt belongs to the early high-temperature mineral phases inherited from the older Proterozoic—Archean main volcanism, while the time of formation of this layer of amphibolites dates back to the age of 2.4 billion years—the Early Karelian era of the Proterozoic.

Abstract Image

科拉超深钻孔深层中的原生钴
摘要 通过采用多种局部分析方法(分析扫描电子显微镜、电子反向散射衍射),在科拉超深钻孔(SG-3)9630 米深处的闪长岩中发现了原生钴。所研究的闪长岩是一种细粒黑云母岩,主要由镁铁角闪石组成,含有原生金属、碲化物、硫碲化物和硫化物(Au、Ag、Pd、Bi、Cu、Pb、Zn、Sb 和 Fe)。确定了原生钴中不含包括铁在内的重要杂质,并确定其属于六方α-修饰。研究表明,在对致密辉石基体进行离子抛光时暴露出的金属钴颗粒不可能是在钻探和样品制备过程中引入样品的杂质。显然,钴的形成不仅早于含钴闪长岩的逆变质阶段和随后的热液加工阶段,而且很可能早于该岩石的沉积原岩形成阶段。也就是说,原生钴属于较早的原生代-阿尔川主火山活动遗留下来的早期高温矿物相,而这层闪长岩的形成时间可以追溯到 24 亿年前--原生代的早卡累利阿时代。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Geology of Ore Deposits
Geology of Ore Deposits 地学-地质学
CiteScore
1.10
自引率
14.30%
发文量
24
审稿时长
6-12 weeks
期刊介绍: Geology of Ore Deposits is a periodical covering the topic of metallic and nonmetallic mineral deposits, their formation conditions, and spatial and temporal distribution. The journal publishes original scientific articles and reviews on a wide range of problems in theoretical and applied geology. The journal focuses on the following problems: deep geological structure and geodynamic environment of ore formation; distribution pattern of metallogenic zones and mineral deposits; geology and formation environment of large and unique metallic and nonmetallic deposits; mineralogy of metallic and nonmetallic deposits; physicochemical and isotopic characteristics and geochemical environment of ore deposition; evolution of ore-forming systems; radiogeology and radioecology, economic problems in exploring, developing, and mining of ore commodities.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信