Synthesis of NiFe2O4 Photocatalyst to Apply for Treatment of Residual Tetracycline in Aqueous Environment with Addition of H2O2

Dang Minh Duc, Cat Minh Hang, Dinh Tuong Van, Nguyen Viet Khoa, Tran Thuy Linh, Nguyen Thi Hanh, Pham Thanh Dong
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Abstract

In the study, NiFe2O4 was successfully synthesized by hydrothermal method for treatment of residual tetracycline (TC) in aqueous environment. The study also investigated effects of H2O2 as electron an acceptor to enhance TC photocatalytic degradation of the synthesized NiFe2O4. The properties of synthesized materials were determined by scanning electron microscopy (SEM), X-ray diffraction (XRD), UV-Vis absoprtion spectroscopy (UV-VIS) and vibrating sample magnetometer (VSM) systems. The obtained results indicated that the synthesized NiFe2O4 were nano-particles with average size of approximately 50 nm. The synthesized NiFe2O4 also exhibited high visible light absorption and magnetic ability. The TC removal results indicated that the NiFe2O4 adsorbed certain amount of tetracycline under dark condition. Under visible light, the NiFe2O4 further degraded significant tetracycline amount. Finally, the study investigated that H2O2 effectively acted as electron acceptor for hydroxyl radical production to degrade tetracycline.
合成 NiFe2O4 光催化剂,用于处理水环境中添加 H2O2 的残留四环素
该研究采用水热法成功合成了 NiFe2O4,用于处理水环境中的残留四环素(TC)。研究还考察了 H2O2 作为电子受体对提高合成的 NiFe2O4 光催化降解四环素的效果。通过扫描电子显微镜(SEM)、X 射线衍射(XRD)、紫外可见吸收光谱(UV-VIS)和振动样品磁力计(VSM)系统测定了合成材料的性质。结果表明,合成的 NiFe2O4 为纳米颗粒,平均尺寸约为 50 纳米。合成的 NiFe2O4 还具有较高的可见光吸收能力和磁性。TC 去除结果表明,在黑暗条件下,NiFe2O4 能吸附一定量的四环素。在可见光条件下,NiFe2O4 进一步降解了大量的四环素。最后,研究还发现 H2O2 可有效地作为电子受体产生羟基自由基来降解四环素。
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