CHARACTERIZATION OF FATTY ACID ETHYL ESTER BIODIESEL (CWO100) PRODUCED FROM COMPOSITE WASTE OILS, ETHANOL AND KOH

A. G. Taiwo, O. Shoyemi, M. A. Adepoju, A. A. Ibikunle
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Abstract

There is an urgent need to convert Composite waste oils (CWOs) from domestic and industrial sources using circular system thinking approach due to the growing concern of their socio-economic, environmental and governance effects and impacts of increased human anthropogenic activities. CWO was first pre-treated by sieving, heated to reduce moisture/water concentration and the acid value lowered with the addition of sufficient KOH, then base transesterification reaction with ethanol (1:1), 1% KOH at 700C for 2 h. The physio-chemical and fuel properties of the CWO100 was analyzed using standard analytical methods, and the data statistically using SPSS version 20.0. CWO100 (FAEE) has lowest value of water and sediment, acid value, free fatty acid, carbon residue and sulphur, and the highest values for viscosity, specific gravity, density, colour, flash point, iodine. Most of its parameters are within the ASTM/EN standards except in CWOs that requires pre-treatment. CWO100 is better than petroleum diesel and can be applied in diesel engines, plants with little or no modification as a major alternative now and thereafter.
用复合废油、乙醇和甲醇生产的脂肪酸乙酯生物柴油(CWO100)的特性分析
由于人们日益关注复合废油对社会经济、环境和治理的影响以及人类活动的增加所带来的影响,因此迫切需要采用循环系统思维方法对来自家庭和工业的复合废油(CWOs)进行转化。首先对 CWO 进行筛分预处理,加热以降低水分/水的浓度,并通过添加足够的 KOH 来降低酸值,然后与乙醇(1:1)和 1%的 KOH 在 700C 下进行 2 小时的碱酯交换反应。CWO100(FAEE)的水分和沉淀物、酸值、游离脂肪酸、残炭和硫的值最低,而粘度、比重、密度、颜色、闪点和碘的值最高。除了需要预处理的 CWO 外,其大部分参数都符合 ASTM/EN 标准。CWO100 优于石油柴油,可用于柴油发动机和工厂,几乎无需改装,是目前和今后的主要替代品。
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