Detection of Heavy Metals in Some Edible Grains Obtained from Two Markets in Bauchi Metropolis, Nigeria

Aisha Mustapha, Ahmad Abdul Hameed, M. Yakubu
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Abstract

This study investigated the level of heavy metals (Cd, Cr, Cu, Fe, Pb and Zn) in grains sold in Central and Muda Lawal markets in Bauchi.  Our objectives include assessing heavy metal concentrations in the grains and evaluating associated health risks. We utilized Atomic  Absorption Spectrophotometry following acid digestion of grains to determine heavy metal concentrations. In Central market-sourced crops, the mean concentrations of Cd, Cr, Cu, Fe, Pb, and Zn were 0.06, 0.49, 0.21, 1.16, 0.15, and 0.17mg/kg respectively. Meanwhile,  crops from Muda Lawal market exhibited mean concentrations of 0.06, 0.58, 0.17, 1.62, 0.1, and 0.22 mg/kg for Cd, Cr, Cu, Fe, Pb, and Zn,  respectively. Cd, Cr, Cu, Pb, and Zn levels were below the permissible limits. However, Fe exceeded permissible limits in small beans, Syria  maize, and white guinea corn from Central market, as well as in Syria maize, Pearl millet II, and white guinea corn from Muda Lawal  market. The daily intake of Cd, Cu, and Pb from most studied crops exceeded the oral reference dose, posing potential health risks.  Conversely, Cr, Fe, and Zn intake levels were within acceptable limits, posing minimal health risks. Hazard quotient and hazard index  values were below 1, suggesting that crop consumption is unlikely to pose health risks. 
从尼日利亚包奇市两个市场获得的一些食用谷物中重金属的检测
本研究调查了包奇中部和 Muda Lawal 市场所售谷物中的重金属(镉、铬、铜、铁、铅和锌)含量。 我们的目标包括评估谷物中的重金属浓度以及相关的健康风险。在对谷物进行酸消化后,我们使用原子吸收分光光度法来确定重金属浓度。在中部市场采购的农作物中,镉、铬、铜、铁、铅和锌的平均浓度分别为 0.06、0.49、0.21、1.16、0.15 和 0.17 毫克/千克。与此同时,Muda Lawal 市场农作物中的镉、铬、铜、铁、铅和锌的平均浓度分别为 0.06、0.58、0.17、1.62、0.1 和 0.22 毫克/千克。镉、铬、铜、铅和锌的含量均低于允许限值。不过,中部市场的小豆、叙利亚玉米和白豚鼠玉米以及 Muda Lawal 市场的叙利亚玉米、珍珠粟 II 和白豚鼠玉米中的铁含量超过了允许限值。大多数研究作物中的镉、铜和铅的日摄入量都超过了口服参考剂量,对健康构成潜在风险。 相反,铬、铁和锌的摄入量在可接受范围内,对健康的危害极小。危害商数和危害指数值低于 1,表明食用农作物不太可能对健康造成危害。
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