GREEN SYNTHESIS OF TITANIUM OXIDE (TIO2) NANOPARTICLES USING Phyllanthus Niruri AND ASSESSMENT OF ITS PHYSIOCHEMICAL PARAMETERS IN WASTEWATER TREATMENT

H. Yunusa, K. I. Omoniyi, S. E. Abechi, S. D. Sani, A. O. Ugwoke, N. Imam
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Abstract

This study investigates the green synthesis of titanium oxide (TiO2) nanoparticles, NPs and assessment of its physiochemical parameters in wastewater treatment. The methanol plant extract of Phyllanthus niruri was utilized for the biosynthesis of titanium oxide NPs. The preliminary phytochemical screening carried out on Phyllanthus niruri plant extract was conducted to identify the bioactive compounds such as alkaloids, flavonoids, tannins, saponins, terpenoids, anthraquinones, glycosides and steroids which may be responsible for stabilizing the nanoparticles synthesized. In the treatment of the industrial wastewater sample; the result indicated that the use of the synthesized titanium oxide nanoparticles led to percentage reduction of 67.21%, 58.96%, 91.19%, 75.56% and 94.67% for BOD, COD, turbidity, oil and grease and phosphate respectively, in the raw wastewater; and was more effective than the use of commercial titanium oxide NPs. The study indicates that synthesis of titanium oxide NPs using Phyllanthus niruri is a better alternative to chemical synthesis of NPs, the green synthesized material is eco-friendly and can serve as a treatment for industrial effluents.
利用 Phyllanthus Niruri 绿色合成氧化钛(TIO2)纳米颗粒并评估其在废水处理中的物理化学参数
本研究探讨了氧化钛(TiO2)纳米颗粒(NPs)的绿色合成及其在废水处理中的理化参数评估。研究利用 Phyllanthus niruri 的甲醇植物提取物进行氧化钛 NPs 的生物合成。对 Phyllanthus niruri 植物提取物进行了初步植物化学筛选,以确定生物活性化合物,如生物碱、黄酮类、单宁酸、皂甙、萜类、蒽醌类、苷类和类固醇,这些化合物可能对合成的纳米粒子起到稳定作用。在处理工业废水样本时,结果表明,使用合成的纳米氧化钛颗粒可使原废水中的生化需氧量、化学需氧量、浊度、油脂和磷酸盐的百分比分别降低 67.21%、58.96%、91.19%、75.56% 和 94.67%,比使用商业氧化钛 NPs 更有效。该研究表明,使用 Phyllanthus niruri 合成氧化钛 NPs 是化学合成 NPs 的一种更好的替代方法,这种绿色合成材料对环境友好,可作为工业废水的一种处理方法。
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