Deoxygenation of N-heterocyclic N-oxides with Selectfluor and disulfane

IF 2 3区化学 Q2 CHEMISTRY, ORGANIC

Journal of Heterocyclic Chemistry Pub Date : 2024-04-14 DOI:10.1002/jhet.4818

Muhammed Hanifi Çelikoğlu, Sefa Uçar, Bilal Nişancı

引用次数: 0

Abstract

Herein, we describe a metal-free methodology using Selectfluor with disulfane, for the deoxygenation of N-heterocyclic N-oxides (33 examples). This effective, robust, and simple methodology enables the synthesis of various deoxygenated analogues from a wide range of N-heterocyclic N-oxide cores at room temperature in short reaction times with quantitative yields.

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用 Selectfluor 和二硫化钼对 N-杂环 N-氧化物进行脱氧反应

在此，我们介绍了一种使用 Selectfluor 和二硫环进行 N-杂环 N-氧化物脱氧的无金属方法（33 例）。这种方法有效、稳健、简单，能在室温下以较短的反应时间和定量的产率从多种 N-杂环 N-氧化物核心合成各种脱氧类似物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Heterocyclic Chemistry 化学-有机化学

CiteScore

5.20

自引率

4.20%

发文量

177

审稿时长

3.9 months

期刊介绍： The Journal of Heterocyclic Chemistry is interested in publishing research on all aspects of heterocyclic chemistry, especially development and application of efficient synthetic methodologies and strategies for the synthesis of various heterocyclic compounds. In addition, Journal of Heterocyclic Chemistry promotes research in other areas that contribute to heterocyclic synthesis/application, such as synthesis design, reaction techniques, flow chemistry and continuous processing, multiphase catalysis, green chemistry, catalyst immobilization and recycling.