REE Mineralization in Alkaline Rhyolites of the Pechalninskii Ore Field (Northeast Russia)

IF 0.7 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY
A. V. Grigorieva, A.V. Volkov, N. V. Sidorova
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Abstract

For the first time by the method of scanning electron microscopy, REE mineralization studies are conducted in alkaline rhyolites of the Pechalninskii ore field (Northeast Russia), a potentially large-volume source of HREEs. It is shown using the methods of electron microprobe analysis and cathodoluminescence that microcrystalline aggregates of pyroxenes and/or amphiboles in alkaline rhyolites contain the finest inclusions of REE segregations (5–7 µm). Using SEM, it is determined that the largest segregation is cerium phosphate. Concentrically zonal and radial-fibrous REE segregations are revealed in the relics of titanomagnetite crystals by EDS. The first ones are represented by silicates enriched with Y and REEs and the content of each REE varies regularly from the center to the edge. The radial-fibrous aggregates are represented by oxides and/or carbonates containing REEs (La, Ce, and Nd predominate). The results obtained can be used in the development of enrichment technology.

Abstract Image

Pechalninskii 矿田(俄罗斯东北部)碱性流纹岩中的 REE 成矿作用
摘要首次采用扫描电子显微镜方法,对俄罗斯东北部佩查尔宁斯基矿区的碱性流纹岩进行了 REE 矿化研究,该矿区可能是 HREEs 的大量来源。使用电子微探针分析和阴极发光的方法表明,碱性流纹岩中的辉石和/或闪石微晶聚集体含有最细小的 REE 分离包裹体(5-7 微米)。利用扫描电子显微镜,可以确定最大的偏析物是磷酸铈。通过 EDS,在钛磁铁矿晶体遗迹中发现了集中的带状和径向纤维状 REE 偏析。前者以富含 Y 和 REE 的硅酸盐为代表,每种 REE 的含量从中心到边缘有规律地变化。径向纤维状聚集体由含有 REEs(主要是 La、Ce 和 Nd)的氧化物和/或碳酸盐组成。所获得的结果可用于开发富集技术。
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来源期刊
Doklady Earth Sciences
Doklady Earth Sciences 地学-地球科学综合
CiteScore
1.40
自引率
22.20%
发文量
138
审稿时长
3-6 weeks
期刊介绍: Doklady Earth Sciences is a journal that publishes new research in Earth science of great significance. Initially the journal was a forum of the Russian Academy of Science and published only best contributions from Russia. Now the journal welcomes submissions from any country in the English or Russian language. Every manuscript must be recommended by Russian or foreign members of the Russian Academy of Sciences.
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