Distribution Patterns of the Main Structural-Group Parameters of Crude Oils from the Timan–Pechora Oil-and-Gas Basin, According to 1Н NMR Data

IF 1.3 4区 工程技术 Q3 CHEMISTRY, ORGANIC
M. B. Smirnov, N. A. Vanyukova
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Abstract

A representative set of crude oils from the Timan–Pechora oil-and-gas basin (OGB) (75 samples of crude oils and natural-gas condensates from 51 fields) was studied, and data on the structural-group composition of the crude oils from this field were obtained. The distributions of all the parameters are far from the normal distribution. Therefore, only methods of nonparametric statistics can be used for the data processing. Among Timan–Pechora crudes, there are samples with abnormally high content of unsaturated compounds of radiogenic nature. Their highest concentration corresponds to the irradiation dose of no less than 11 MGy. On the whole, Timan–Pechora crudes differ from those studied previously (from the West Siberian, East Siberian, Volga–Urals, and North Caucasus OGBs) primarily in the content of monoaromatic components. The Timan–Pechora crudes occupy an intermediate position between those from West Siberia and Volga–Urals, on the one hand, and from East Siberia and North Caucasus, on the other hand. As compared to crude oils of the second group, Timan–Pechora crudes have considerably higher content of aromatic compounds. In the content of bi- and polycyclic aromatic components, Timan–Pechora crudes are close to those from West Siberia and Volga–Urals. All the large tectonic structures are combined in four groups with respect to crude oil composition: (1) Varandei–Adzva zone + Khoreivei and Kos’yu-Rogovskaya depressions; (2) Izhma–Pechora syneclise + Upper Pechora depression; (3) Pechora–Kozhva aulacogene; and (4) East Timan megalithic bank.

Abstract Image

根据 1Н NMR 数据得出的蒂曼-伯朝拉油气盆地原油主要结构组参数的分布模式
摘要 研究了 Timan-Pechora 油气盆地(OGB)具有代表性的一组原油(来自 51 个油田的 75 个原油和天然气凝析油样本),并获得了该油田原油结构组成的数据。所有参数的分布都远离正态分布。因此,只能使用非参数统计方法进行数据处理。在 Timan-Pechora 原油中,有一些样本的放射性不饱和化合物含量异常高。其最高含量与不少于 11 MGy 的辐照剂量相对应。总体而言,季曼-伯朝拉原油与之前研究的原油(来自西西伯利亚、东西伯利亚、伏尔加-乌拉尔和北高加索 OGB)的不同之处主要在于单芳香族成分的含量。铁曼-伯朝拉原油处于西西伯利亚和伏尔加-乌拉尔原油与东西伯利亚和北高加索原油之间的中间位置。与第二类原油相比,蒂曼-伯朝拉原油的芳香族化合物含量要高得多。在双环和多环芳烃成分含量方面,季曼-伯朝拉原油与西西伯利亚和伏尔加-乌拉尔地区的原油接近。就原油成分而言,所有大型构造分为四组:(1) Varandei-Adzva 区 + Khoreivei 和 Kos'yu-Rogovskaya 凹陷;(2) Izhma-Pechora syneclise + Upper Pechora 凹陷;(3) Pechora-Kozhva aulacogene;(4) East Timan megalithic bank。
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来源期刊
Petroleum Chemistry
Petroleum Chemistry 工程技术-工程:化工
CiteScore
2.50
自引率
21.40%
发文量
102
审稿时长
6-12 weeks
期刊介绍: Petroleum Chemistry (Neftekhimiya), founded in 1961, offers original papers on and reviews of theoretical and experimental studies concerned with current problems of petroleum chemistry and processing such as chemical composition of crude oils and natural gas liquids; petroleum refining (cracking, hydrocracking, and catalytic reforming); catalysts for petrochemical processes (hydrogenation, isomerization, oxidation, hydroformylation, etc.); activation and catalytic transformation of hydrocarbons and other components of petroleum, natural gas, and other complex organic mixtures; new petrochemicals including lubricants and additives; environmental problems; and information on scientific meetings relevant to these areas. Petroleum Chemistry publishes articles on these topics from members of the scientific community of the former Soviet Union.
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