GC/MS Analysis of Essential oil distilled from Arum rupicola Boiss. var. rupicola (Araceae)

H. Demiray, Betül Demirci, Hasan Yildirim
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Abstract

Aim: Arum rupicola Boiss. var. rupicola with a vernacular name of Dağ Sorsalı, are used etnobotanically for hemorroid, eczema, rheumatism, and cancer. Essential oil combination of A. rupicola var. rupicola, under the lower risk (lc) threatened category because of the excess gathering was investigated. Methods: The above ground samples of Arum rupicola Boiss. var. rupicola was collected from Palamut province of Antalya (Kaş) and essential oil was taken by hydrodistillation method with Clevenger apparatus. The essential oil composition was analysed by Gas chromatography (GC) and Gas chromatography/Mass Spectrometry (GC/MS) systems simultaneously. Results: As a result of, (E)-geranyl acetone (15%) was the main compound while hexahydrofarnesyl acetone (9.2%), nonanal (6.8%), heptacosan (6.5%), farnesyl acetone (5.0%), tricosan (4.9%), ve 2-dodecanone (3.8%) followed. Conclusion: Farnesyl acetone (5%) and hexahydrofarnesyl acetone (9.2%) sesquiterpenes were new records for A. rupicola var. rupicola volatile oil content. The only species is Arum creticum consisting α-farnesene (95%) as its taxonomical feature. A. rupicola var. rupicola has farnesyl acetone and hexahydrofarnesyl aceton being known a flagy and odourless species.
从 Arum rupicola Boiss.
目的:Arum rupicola Boiss.由于过量采集,A. rupicola var. rupicola 属于低风险(lc)受威胁类别,本研究对其精油组合进行了调查。研究方法从安塔利亚(Kaş)的帕拉穆特省采集了 Arum rupicola Boiss.精油成分同时由气相色谱法(GC)和气相色谱/质谱法(GC/MS)系统分析。结果:结果表明,(E)-香叶基丙酮(15%)是主要化合物,其次是六氢香叶基丙酮(9.2%)、壬醛(6.8%)、七堇花苷(6.5%)、香叶基丙酮(5.0%)、三堇花苷(4.9%)、ve 2-十二酮(3.8%)。结论法呢基丙酮(5%)和六氢法呢基丙酮(9.2%)倍半萜是鲁冰花变种挥发油含量的新记录。唯一的物种是以 α-法呢烯(95%)为分类特征的 Arum creticum。rupicola var. rupicola 具有法呢基丙酮和六氢法呢基丙酮,是已知的无旗无味物种。
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