Механічні властивості аморфних металевих сплавів системи Al87(Ni,Fe)8(REM)5 після короткочасного відпалу

K. Khrushchyk, A. Barylski, K. Aniolek, M. Karolus, L. Boichyshyn
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Abstract

The phase transition temperatures for amorphous metals based on aluminum Al87(Ni,Fe)8(REM)5 system were determined by differential scanning calorimetry (DSC).  The mechanisms of formation and growth of nanocrystals in an amorphous matrix were predicted using kinetic models (Matusita model). It was found that after annealing at the temperature of stable nanocrystalline growth, an X-ray amorphous structure with a volume fraction of disordered nanocrystalline phases of solid state of Al(X), GdFe2, AlFe2Ni, GdFe2 for the amorphous metal alloy (AMA) Al87Y4Gd1Ni4Fe4 alloy and microcrystalline phases of solid state of Al(X), GdFe2 AlFe2Ni for the Al87Gd5Ni4Fe4 alloy are formed, which significantly affects the mechanical properties of the Al87(Ni,Fe)8(REM)5 system. The effect of annealing on the mechanical properties of amorphous aluminum-based alloys was investigated using Oliver-Pharr and Young's modulus methods it was found that thermal modification of AMAs: Al87Gd5Ni4Fe4 as a result of heat treatment of AMAs from 5 to 15 min., the microhardness increases from 0.20 GPa to 2.75 GPa, and when heat treated for 60 min at a temperatures of T3 = 645±5 K, 647±5 K, it decreases to 0.35 GPa and 0.45 GPa, respectively.
短期退火后 Al87(Ni,Fe)8(REM)5 系非晶态金属合金的机械特性
通过差示扫描量热法(DSC)测定了基于铝 Al87(Ni,Fe)8(REM)5体系的非晶态金属的相变温度。 利用动力学模型(Matusita 模型)预测了纳米晶体在非晶基体中的形成和生长机制。研究发现,在纳米晶体稳定生长的温度下退火后,X 射线无定形结构中的无序纳米晶体相的体积分数为 Al(X)、GdFe2、AlFe2Ni、在非晶态金属合金 (AMA) Al87Y4Gd1Ni4Fe4 合金中形成 GdFe2,在 Al87Gd5Ni4Fe4 合金中形成 Al(X)、GdFe2 AlFe2Ni 固态微晶相,这极大地影响了 Al87(Ni,Fe)8(REM)5 体系的力学性能。使用奥利弗-帕尔法和杨氏模量法研究了退火对非晶铝基合金机械性能的影响:Al87Gd5Ni4Fe4 热处理 5 至 15 分钟后,显微硬度从 0.20 GPa 增至 2.75 GPa,而在 T3 = 645±5 K、647±5 K 温度下热处理 60 分钟后,显微硬度分别降至 0.35 GPa 和 0.45 GPa。
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