Complex Concentrated Alloy Catalyst of AlCrFeCoNi for Heterogeneous degradation of Rhodamine B

K. C. Sembiring, I. Fahrezi, Muhdarina Muhdarina, Ahmad Afandi
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Abstract

The Fe-based catalysts have attracted good attention due to their earth abundance and low toxicity with good Fenton-like performance. However, the narrow pH working range and iron-containing sludge produced during the reaction drove the necessary of developing a potential catalyst in the corresponding application. High entropy alloy that now expands to complex concentrated alloy (CCA) represents a new class of material owing to a broader range of functional and structural properties. A new application of CCA as a catalyst for catalytic degradation of azo dyes has already been a scientific research hotspot. AlCrFeCoNi CCA powder has been successfully synthesized by mechanical alloying (MA) method using a vertical planetary ball mill. Based on the characterization, the catalyst possessed a spherical morphology with a particle size range of 3.5-12.6 mm. The catalyst exhibited photo-Fenton performance up to 85.3% which would be a promising Fenton-like catalyst for wastewater treatment. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).
用于罗丹明 B 异构降解的 AlCrFeCoNi 复合浓缩合金催化剂
铁基催化剂因其丰富的地球资源、低毒性和良好的 Fenton-like 性能而备受关注。然而,由于 pH 值工作范围较窄,且反应过程中会产生含铁污泥,因此有必要在相应的应用领域开发一种潜在的催化剂。高熵合金现已扩展为复杂浓缩合金(CCA),由于具有更广泛的功能和结构特性,它代表了一类新材料。作为催化降解偶氮染料的催化剂,CCA 的新应用已成为科学研究的热点。利用立式行星球磨机,通过机械合金化(MA)方法成功合成了铝铬铁钴镍(AlCrFeCoNi)CCA 粉末。根据表征,催化剂呈球形,粒径范围为 3.5-12.6 毫米。该催化剂的光-芬顿性能高达 85.3%,有望成为一种用于废水处理的类芬顿催化剂。作者版权所有 © 2024 年,BCREC 出版集团出版。本文采用 CC BY-SA 许可协议 (https://creativecommons.org/licenses/by-sa/4.0) 公开发表。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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