Inhibition of Acid Descaling and Pickling Effects on API 5CT Carbon Steel Using Schiff Base Ligand (C24H21N5O2) in 1 M H2SO4 Solution

B. Ugi
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Abstract

The objective of this paper was to investigate the inhibition of acid descaling and pickling effects on API 5CT carbon steel using Schiff base ligand (C24H21N5O2) in 1 M H2SO4 solution using  Potentiodynamic Polarization (PDP), Electrochemical Impedance Spectroscopy (EIS) and Weight Loss (WL) techniques. FTIR spectroscopy shows that there was a strong adsorption of SFBL on the carbon steel surface due to formation of a complex surface film. Corrosion rate of carbon steel decreased exceedingly from 0.0155 to 0.0002 while inhibition efficiency of SFBL rose from 78.8 % to 98.9 % between 20 ppm and 100 ppm respectively. PDP measurements revealed a mixed type inhibitor. EIS measurement reveals that the increasing charge transfer resistance was directly proportional to the increase inhibitor concentration and the double layer capacitance dropped from 1.98 to 0.61 indicating a stronger inhibition.
在 1 M H2SO4 溶液中使用希夫碱配体 (C24H21N5O2) 抑制 API 5CT 碳钢的酸性除锈和酸洗效果
本文旨在利用电位极化(PDP)、电化学阻抗谱(EIS)和失重(WL)技术,研究希夫碱配体(C24H21N5O2)在 1 M H2SO4 溶液中对 API 5CT 碳钢的酸除锈和酸洗抑制作用。傅立叶变换红外光谱显示,由于形成了复杂的表面膜,SFBL 在碳钢表面有很强的吸附力。碳钢的腐蚀率从 0.0155 大大降低到 0.0002,而 SFBL 的抑制效率在 20 ppm 和 100 ppm 之间分别从 78.8 % 上升到 98.9 %。PDP 测量显示出一种混合型抑制剂。EIS 测量显示,电荷转移电阻的增加与抑制剂浓度的增加成正比,双层电容从 1.98 降至 0.61,表明抑制作用更强。
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