Nano-Titanium Dioxide Filler Particles in Soybean Methyl Ester for an Improvement of Electrical Breakdown Strength of Soybean Vegetable Oil as a Transformer Oil Substitute

Nichakorn Khonchaiyaphum, T. Wongwuttanasatian, A. Suksri
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Abstract

Power transformers use mineral oil as an insulating liquid due to its excellent dielectric properties. However, mineral oil is a non-renewable resource and is toxic to the environment when leaked. The purpose of this research is to examine vegetable oil containing nanotitanium dioxide as a substitute for mineral transformer oil. Vegetable insulating oils are environmentally benign and have good breakdown voltage (BV) and high ignition points that can decompose naturally in the event of a leak. Nevertheless, the high viscosity of vegetable oil slows down the flow rate in the transformer cooling. To overcome this problem, the process of transesterification was used to produce soybean methyl ester (SBME). SBME is used as an insulating liquid including composite filler of titanium dioxide (TiO2) nanoparticles. Electrical breakdown voltage (BV) tests were performed following ASTM D1816 standards. Results demonstrated that SBME has a greater BV than natural soybean oil. Also, the addition TiO2 nanoparticles increases the BV of the SBME’s mixture. All cases of nanoparticle methyl ester (NPME) conducted in the experiments exhibited a BV higher than 28 kV which is well above the standard value.
大豆甲酯中的纳米二氧化钛填料颗粒用于提高大豆植物油作为变压器油替代品的电气击穿强度
由于矿物油具有出色的介电特性,电力变压器使用矿物油作为绝缘液体。然而,矿物油是不可再生资源,泄漏后对环境有毒。本研究的目的是研究含有纳米二氧化钛的植物油作为矿物变压器油的替代品。植物绝缘油对环境无害,具有良好的击穿电压(BV)和高燃点,在发生泄漏时可自然分解。然而,植物油的高粘度会降低变压器冷却过程中的流速。为了克服这个问题,我们采用了酯交换工艺来生产大豆甲酯(SBME)。SBME 用作绝缘液体,包括纳米二氧化钛 (TiO2) 复合填料。按照 ASTM D1816 标准进行了电击穿电压 (BV) 测试。结果表明,SBME 的 BV 值高于天然大豆油。此外,添加 TiO2 纳米粒子还能提高 SBME 混合物的 BV。实验中所有纳米颗粒甲酯(NPME)的 BV 值均高于 28 kV,远远高于标准值。
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