Impact of Hurricanes, Tropical Storms, and Coastal Extratropical Storms on Indoor Air VOC Concentrations

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Chris Lutes, Victoria Boyd, Gwen Buckley, Laurent Levy, Kate Bronstein, John H. Zimmerman, Alan Williams, Brian Schumacher
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Abstract

Understanding vapor intrusion (VI) temporal variability is key for the design of sampling strategies intended to assess reasonable maximum exposure of indoor air concentrations of volatile organic compounds (VOCs) as well as risk evaluation and mitigation planning. VI temporal variability has previously been shown to be dependent on the complex interactions of multiple independent variables—meteorological, hydrogeological, and human behavioral. Several meteorological variables, including barometric pressure, wind speed, and rainfall, are linked during tropical and extratropical storm events. High-frequency meteorological and indoor VOC data from a series of seven tropical storms and four extratropical storms were collected at a single industrial building with multiple heating, ventilation, and air conditioning (HVAC) zones. The storms and sampling zones showed a variety of effects on trichloroethylene (TCE) concentrations in indoor air. In one zone (supply room), increases in TCE concentrations often, but not always, closely coincided with decreasing barometric pressure, sustained wind speeds over 32 km/h (20 mph), and differential pressures indicating subslab to indoor flow. A second zone, in a restroom, did not show a consistent pattern of temporal correlation between meteorological factors and indoor air concentrations. While peak indoor air concentrations may be associated with the passage of cyclonic storms at some sampling locations, this does not appear to be generalizable to all sampling locations. The observed increase in indoor air concentration potentially attributable to these storms is typically less than an order of magnitude and the duration ranges from a day to a week.

飓风、热带风暴和沿海外热带风暴对室内空气中挥发性有机化合物浓度的影响
了解水汽入侵(VI)的时间变异性对于设计旨在评估室内空气中挥发性有机化合物(VOC)浓度的合理最大暴露量的采样策略以及风险评估和缓解规划至关重要。以前的研究表明,VI 的时间变异性取决于气象、水文地质和人类行为等多个独立变量的复杂相互作用。包括气压、风速和降雨量在内的几个气象变量在热带和外热带暴风雨事件期间相互关联。我们在一栋有多个供暖、通风和空调(HVAC)区域的工业建筑中收集了来自七次热带风暴和四次外热带风暴的高频气象和室内挥发性有机化合物数据。风暴和采样区对室内空气中的三氯乙烯 (TCE) 浓度产生了各种影响。在一个采样区(供应室),TCE 浓度的增加往往与气压下降、持续风速超过 32 千米/小时(20 英里/小时)以及表明地下向室内流动的压差密切相关,但并非总是如此。第二个区域位于洗手间内,气象因素与室内空气浓度之间的时间相关性并不一致。虽然在某些采样地点,室内空气浓度的峰值可能与气旋风暴的通过有关,但这似乎并不能推广到所有采样地点。观测到的室内空气浓度增加可能与这些风暴有关,但通常小于一个数量级,持续时间从一天到一周不等。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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