Self-organisation in gabbroic cumulates: a new patterning mechanism driven by differential migration of immiscible liquids in a crystal mush?

IF 3.5 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS
Marian B Holness
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引用次数: 0

Abstract

Self-organisation in plutonic igneous rocks has been suggested to form by a variety of mechanisms including oscillatory nucleation and growth, competitive particle growth (CPG), and preferential dissolution and re-precipitation during fluid infiltration enhanced by compaction, with driving forces including reduction of the interfacial energy budget by either Ostwald ripening or because the energy of boundaries between two grains of the same mineral is less than that between two grains of different minerals. An investigation of the Stillwater inch-scale layering shows that the CPG patterning mechanism leaves a characteristic microstructural signature preserving evidence for a highly interconnected melt in textural equilibrium, and slow super- and sub-solidus cooling: such a signature is also preserved in chromite-bearing fine-scale layers in the Bushveld intrusion. The cm-scale micro-rhythmic layering of the Skaergaard intrusion, superimposed on single modally-graded layers, does not have these microstructural features. Furthermore, the energy of all relevant inter-phase grain boundaries in the Skaergaard gabbros is less than that of grain boundaries involving only one mineral, viscous compaction was not a significant process in the Skaergaard intrusion, and patterning by oscillatory nucleation and growth is precluded by the fact that the micro-rhythmic layering is superimposed on modally graded layers formed by sedimentation. A new patterning mechanism is proposed, operational only in intrusions in which the interstitial liquid of the crystal mush intersects a binode and splits into two immiscible conjugates. Cm-scale separation of the immiscible conjugate liquids in a compositionally-graded mush, due to both gravity and capillary forces, leads to layering due to differences in their wetting properties. The positive feedback required for pattern formation is due to the two immiscible conjugates predominantly crystallising the minerals which they preferentially wet.
辉长岩积聚体的自组织:由晶体蘑菇中不相溶液体的不同迁移驱动的新模式化机制?
有人认为,柱状火成岩中的自组织是通过各种机制形成的,包括振荡成核和生长、竞争性颗粒生长(CPG)、流体渗透过程中的优先溶解和再沉淀,这些机制的驱动力包括奥斯特瓦尔德熟化(Ostwald ripening)导致的界面能量预算减少,或者是由于相同矿物的两个晶粒之间的边界能量小于不同矿物的两个晶粒之间的边界能量。对斯蒂尔沃特英寸尺度分层的研究表明,CPG模式机制留下了一种特征性的微结构特征,保留了质地平衡的高度互联熔体以及缓慢的超固结和亚固结冷却的证据:这种特征也保留在布什维尔德侵入体的含铬细尺度层中。斯卡尔加德侵入体的厘米级微节律分层叠加在单一模态分级层上,不具有这些微结构特征。此外,斯卡尔加德辉长岩中所有相关相间晶界的能量都小于只涉及一种矿物的晶界能量,斯卡尔加德侵入体中的粘滞压实过程并不重要,而且由于微节律层理叠加在沉积形成的模态分级层上,因此不可能通过振荡成核和生长形成模式。我们提出了一种新的模式化机制,这种机制只在晶体蘑菇的间隙液体与双节点相交并分裂成两种不相溶共轭物的侵入中起作用。在重力和毛细力的作用下,成分分级蘑菇云中的不溶共轭液体在厘米尺度上分离,由于它们的润湿特性不同而导致分层。图案形成所需的正反馈是由于两种不相溶共轭物主要使它们优先润湿的矿物结晶。
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来源期刊
Journal of Petrology
Journal of Petrology 地学-地球化学与地球物理
CiteScore
6.90
自引率
12.80%
发文量
117
审稿时长
12 months
期刊介绍: The Journal of Petrology provides an international forum for the publication of high quality research in the broad field of igneous and metamorphic petrology and petrogenesis. Papers published cover a vast range of topics in areas such as major element, trace element and isotope geochemistry and geochronology applied to petrogenesis; experimental petrology; processes of magma generation, differentiation and emplacement; quantitative studies of rock-forming minerals and their paragenesis; regional studies of igneous and meta morphic rocks which contribute to the solution of fundamental petrological problems; theoretical modelling of petrogenetic processes.
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