Solvatochromism of a saddle-distorted cationic Zn(II)-porphyrin complex

IF 0.9 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Journal of Porphyrins and Phthalocyanines Pub Date : 2024-03-19 DOI:10.1142/s108842462450007x

Hidemi Ochiai, Tomoya Ishizuka, Hiro Tanaka, Yoshihito Shiota, Kazunari Yoshizawa, Takahiko Kojima

引用次数: 0

Abstract

A saddle-distorted and cationic Zn(II)-porphyrin complex was revealed to exhibit solvatochromism in organic solvents, depending on the donor numbers. The color change was derived from the alteration of the HOMO-LUMO gap caused by the distortion of the porphyrin mean plane due to solvent coordination.

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鞍形扭曲阳离子锌（II）-卟啉配合物的溶解变色作用

研究发现，一种鞍形扭曲的阳离子锌（II）-卟啉配合物在有机溶剂中表现出溶解变色现象，具体取决于供体数目。这种颜色变化源于溶剂配位导致的卟啉平均面变形所引起的 HOMO-LUMO 间隙的改变。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Porphyrins and Phthalocyanines 化学-化学综合

CiteScore

2.10

自引率

20.00%

发文量

审稿时长

1 months

期刊介绍： The Journal of Porphyrins and Phthalocyanines (JPP) covers research in the chemistry, physics, biology and technology of porphyrins, phthalocyanines and related macrocycles. Research papers, review articles and short communications deal with the synthesis, spectroscopy, processing and applications of these compounds.