Influence of washing with sodium lauryl sulphate (SLS) surfactant on different properties of ramie fibres

Murugesan Palaniappan, Sivasubramanian Palanisamy, Thulasi Mani Murugesan, Srinivas Tadepalli, Rashid Khan, Sabbah Ataya, Carlo Santulli
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Abstract

Green composite materials are a means of reducing reliance on synthetic and especially single-use plastics (SUP) and raising public awareness of the need for urgent action to protect the planet. Natural (lignocellulosic) fibres are increasingly utilized as the reinforcement in polymer matrix composites, in search for increased renewability and sustainability. This work concerns the effect of washing ramie (Boehmeria nivea) fibres using sodium lauryl sulphate (SLS) surfactant. The SLS-treated ramie fibres were examined for their morphological, physical, thermal, structural, and mechanical properties by powder X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and tensile testing. SLS treated ramie fibres density and crystallinity index values were 1.23 g/cc and 84.5%, respectively, with a very high cellulose content of 81.3%, because hemicellulose and loose particles were dissolved. SEM images depicted the relevant changes, with no significant damage on treated fibre surfaces. With some assistance from the treatment, fibres initiated their degradation only above 250 °C, culminating at 327 °C, which appears suitable for the manufacturing of composites with the most common matrices.
用十二烷基硫酸钠(SLS)表面活性剂洗涤对苎麻纤维不同特性的影响
绿色复合材料是减少对合成塑料,特别是一次性塑料(SUP)的依赖,提高公众对采取紧急行动保护地球必要性的认识的一种手段。为了提高可再生性和可持续性,越来越多地使用天然(木质纤维素)纤维作为聚合物基复合材料的增强材料。这项研究涉及使用十二烷基硫酸钠(SLS)表面活性剂洗涤苎麻(苧麻)纤维的效果。通过粉末 X 射线衍射 (XRD)、傅立叶变换红外光谱 (FTIR)、热重分析 (TGA)、扫描电子显微镜 (SEM) 和拉伸测试,检测了经 SLS 处理的苎麻纤维的形态、物理、热、结构和机械性能。经 SLS 处理的苎麻纤维密度和结晶度指数值分别为 1.23 g/cc 和 84.5%,纤维素含量高达 81.3%,这是因为半纤维素和松散颗粒被溶解了。扫描电镜图像显示了相关的变化,处理过的纤维表面没有明显的损伤。在处理方法的帮助下,纤维仅在 250 °C 以上才开始降解,最终降解温度为 327 °C。
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