“Exploring the Inhibitory Potential of Acetoxime-Zinc Chloride Adduct in Saline Environments for Mild Steel Corrosion Protection”

IF 1.1 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY
Corrosion Pub Date : 2024-03-12 DOI:10.5006/4398
S. K. Ola, Ishita Chopra, S. Gopalakrishnan, Veena Dhayal
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Abstract

In this work, acetoxime, zinc chloride and acetoxime adduct of zinc chloride, [ZnCl2.2{HON=C(CH3)2}] (ZA) were investigated as corrosion inhibitor's in 3.5%NaCl solution on mild steel. The electrochemical analysis was carried out using polarization measurements and electrochemical impedance technique and surface analysis was done by Scanning electron microscope coupled with Energy-dispersive X-ray spectroscopy. Using surface analysis and electrochemical data it was concluded that an inhibition synergy was developed when ZA was taken instead of acetoxime or zinc chloride alone in solution phase. Scanning electron microscope methods were used to examine the samples surface in the presence of inhibited solutions. The efficiency of inhibition increases with the increasing concentration and attained the values of 97.18% for the 3mM concentration of ZA.
"探索乙酰氧基肟-氯化锌加合物在盐碱环境中保护低碳钢腐蚀的抑制潜力"
在这项工作中,研究了乙酰肟、氯化锌和乙酰肟氯化锌加合物 [ZnCl2.2{HON=C(CH3)2}] (ZA) 在 3.5%NaCl 溶液中对低碳钢的缓蚀作用。电化学分析采用极化测量法和电化学阻抗技术,表面分析采用扫描电子显微镜和能量色散 X 射线光谱法。利用表面分析和电化学数据得出的结论是,在溶液阶段使用ZA代替乙酰肟或氯化锌时,会产生抑制协同作用。研究人员使用扫描电子显微镜方法来检测存在抑制溶液的样品表面。抑制效率随着浓度的增加而提高,在 3mM 浓度的ZA 中达到了 97.18%。
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来源期刊
Corrosion
Corrosion MATERIALS SCIENCE, MULTIDISCIPLINARY-METALLURGY & METALLURGICAL ENGINEERING
CiteScore
2.80
自引率
12.50%
发文量
97
审稿时长
3 months
期刊介绍: CORROSION is the premier research journal featuring peer-reviewed technical articles from the world’s top researchers and provides a permanent record of progress in the science and technology of corrosion prevention and control. The scope of the journal includes the latest developments in areas of corrosion metallurgy, mechanisms, predictors, cracking (sulfide stress, stress corrosion, hydrogen-induced), passivation, and CO2 corrosion. 70+ years and over 7,100 peer-reviewed articles with advances in corrosion science and engineering have been published in CORROSION. The journal publishes seven article types – original articles, invited critical reviews, technical notes, corrosion communications fast-tracked for rapid publication, special research topic issues, research letters of yearly annual conference student poster sessions, and scientific investigations of field corrosion processes. CORROSION, the Journal of Science and Engineering, serves as an important communication platform for academics, researchers, technical libraries, and universities. Articles considered for CORROSION should have significant permanent value and should accomplish at least one of the following objectives: • Contribute awareness of corrosion phenomena, • Advance understanding of fundamental process, and/or • Further the knowledge of techniques and practices used to reduce corrosion.
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