María del Consuelo Mendoza Herrera , Mario Sampedro Cruz , Lydia María Pérez Díaz , José Antonio Rivera Márquez , Laura Orea Flores , Sylvain Bernès , W. T. A. Harrison (Editor)
{"title":"Methyl N-{(1R)-2-[(methoxycarbonyl)oxy]-1-phenylethyl}carbamate","authors":"María del Consuelo Mendoza Herrera , Mario Sampedro Cruz , Lydia María Pérez Díaz , José Antonio Rivera Márquez , Laura Orea Flores , Sylvain Bernès , W. T. A. Harrison (Editor)","doi":"10.1107/S2414314624002220","DOIUrl":null,"url":null,"abstract":"<div><p>The chiral title compound forms supramolecular chains, through N—H⋯O hydrogen bonds between the amide and carboxylate groups.</p></div><div><p>The title molecule, C<sub>12</sub>H<sub>15</sub>NO<sub>5</sub>, is a methyl carbamate derivative obtained by reacting (<em>R</em>)-2-phenylglycinol and methyl chloroformate, with calcium hydroxide as heterogeneous catalyst. Supramolecular chains are formed in the [100] direction, based on N—H⋯O hydrogen bonds between the amide and carboxylate groups. These chains weakly interact in the crystal, and the phenyl rings do not display significant π–π interactions. <span><figure><span><img><ol><li><span>Download : <span>Download high-res image (214KB)</span></span></li><li><span>Download : <span>Download full-size image</span></span></li></ol></span></figure></span> </p></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 3","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624000105","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract
The chiral title compound forms supramolecular chains, through N—H⋯O hydrogen bonds between the amide and carboxylate groups.
The title molecule, C12H15NO5, is a methyl carbamate derivative obtained by reacting (R)-2-phenylglycinol and methyl chloroformate, with calcium hydroxide as heterogeneous catalyst. Supramolecular chains are formed in the [100] direction, based on N—H⋯O hydrogen bonds between the amide and carboxylate groups. These chains weakly interact in the crystal, and the phenyl rings do not display significant π–π interactions.
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