Cu2O-Enhanced Back Surface Field Empowers Selenium-Based TiO2/Sb2Se3 Thin Film Solar Cells to Achieve Efficiency over 32%

IF 1.204 Q3 Energy
Basra Sultana, A. T. M. Saiful Islam, Md. Dulal Haque, Abdul Kuddus
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Abstract

Antimony (Sb) chalcogenides, particularly antimony selenide (Sb2Se3), have gained attention as promising semiconductor materials in order to creat and advancement of competitive solar cells. These materials exhibit a range of desirable qualities, such as excellent absorption rate, ability to modify band gap, and plentiful in the crust of the earth. This article describes an antimony selenide (Sb2Se3) absorber based high-efficient thin film solar cell (TFSC) with copper oxide (Cu2O) as as back surface field (BSF) by dint of Al/ITO/TiO2/Sb2Se3/Cu2O/Ni heterostructure using SCAPS-1D Simulator. This research entails an in-depth assessment of various physical and electrical characteristics of every solar active semiconductorof TiO2,Sb2Se3, and Cu2O covering the thickness of each layer, concentration of carrier doping, defect density in the bulk and at the interface, carrier generation rate together with recombination. Initially, the variation in photovoltaic parameters of open circuit voltage (Voc), short-circuit current density (Jsc), fill factor (FF), power conversion efficiency (PCE), and quantum efficiency (QE) investigated without the BSF layer, followed by a comprehensive analysis on the role of Cu2O BSF layer for enhancing cell’s performance explored systematically. The proposed heterostructure shows improved PCE of over 32% (which was 21% without BSF) with JSC of 37.492 mA/cm2, VOC of 1.024 V, and FF of 83.595%. Thus, the utilisation of a heterostructure comprising Sb2Se3 absorber and copper oxide Cu2O BSF layer demonstrates significant promise in the development and production the high-efficiency greenery thin-film solar cells (TFSCs).

Abstract Image

Cu2O 增强的背表面场使硒基 TiO2/Sb2Se3 薄膜太阳能电池的效率超过 32
摘要锑(Sb)瑀,特别是硒化锑(Sb2Se3),作为一种有前途的半导体材料,在创造和发展有竞争力的太阳能电池方面受到了关注。这些材料表现出一系列令人满意的特性,如出色的吸收率、改变带隙的能力以及在地壳中含量丰富。本文利用 SCAPS-1D 模拟器,通过 Al/ITO/TiO2/Sb2Se3/Cu2O/Ni 异质结构,描述了一种基于硒化锑(Sb2Se3)吸收剂的高效薄膜太阳能电池(TFSC),并以氧化铜(Cu2O)作为背表面场(BSF)。这项研究需要深入评估 TiO2、Sb2Se3 和 Cu2O 等每种太阳能活性半导体的各种物理和电气特性,包括每层的厚度、载流子掺杂浓度、块体和界面上的缺陷密度、载流子生成率和重组。首先,研究了无 BSF 层时开路电压 (Voc)、短路电流密度 (Jsc)、填充因子 (FF)、功率转换效率 (PCE) 和量子效率 (QE) 等光伏参数的变化,然后系统地分析了 Cu2O BSF 层对提高电池性能的作用。所提出的异质结构将 PCE 提高了 32%(无 BSF 时为 21%),JSC 为 37.492 mA/cm2,VOC 为 1.024 V,FF 为 83.595%。因此,利用由 Sb2Se3 吸收体和氧化铜 Cu2O BSF 层组成的异质结构,在开发和生产高效绿色薄膜太阳能电池(TFSCs)方面大有可为。
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来源期刊
Applied Solar Energy
Applied Solar Energy Energy-Renewable Energy, Sustainability and the Environment
CiteScore
2.50
自引率
0.00%
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0
期刊介绍: Applied Solar Energy  is an international peer reviewed journal covers various topics of research and development studies on solar energy conversion and use: photovoltaics, thermophotovoltaics, water heaters, passive solar heating systems, drying of agricultural production, water desalination, solar radiation condensers, operation of Big Solar Oven, combined use of solar energy and traditional energy sources, new semiconductors for solar cells and thermophotovoltaic system photocells, engines for autonomous solar stations.
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