Investigation of the Mechanical and Chemical Stability of Superhydrophobic Coatings Based on Reactive Copolymers of Glycidyl Methacrylate and Fluoroalkyl Methacrylates

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
V. V. Klimov, O. V. Kolyaganova, E. V. Bryuzgin, A. V. Navrotskiy, I. A. Novakov
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引用次数: 0

Abstract

This work is devoted to studying the stability of polymer coatings formed from reactive copolymers of glycidyl methacrylate and fluoroalkyl methacrylates and applied onto textured aluminum and cotton textile surfaces. The stability is determined with respect to the action of aggressive media and mechanical stress. The resulting coatings provide the achievement of long-term stable heterogeneous wetting with initial contact angles as large as 170°, thus preventing the penetration of corrosive agents into the hierarchical structure. The study has shown the influence of the composition of the reactive copolymers containing 3–7 fluorine atoms in a monomer unit on the stability of the polymer coatings with respect to the prolonged exposure to media with different acidities, as well as to cavitation, and abrasive wear.

Abstract Image

Abstract Image

基于甲基丙烯酸缩水甘油酯和甲基丙烯酸氟烷基酯反应共聚物的超疏水涂层的机械和化学稳定性研究
摘要--这项工作致力于研究由甲基丙烯酸缩水甘油酯和甲基丙烯酸氟烷基酯的反应共聚物形成的聚合物涂层在纹理铝和棉纺织品表面上的稳定性。涂层的稳定性取决于侵蚀性介质和机械应力的作用。所得涂层可实现长期稳定的异质润湿,初始接触角可大至 170°,从而防止腐蚀剂渗入分层结构。研究表明,单体单元中含有 3-7 个氟原子的活性共聚物的组成对聚合物涂层在长期暴露于不同酸度的介质以及气蚀和磨料磨损下的稳定性有影响。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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