Selection of graphene as a conductive additive for biomass-based activated carbon electrode in capacitive deionization: acid-treated as a practical approach to reduce graphene content

Abstract

The use of graphene (GE) as a conductive additive for activated carbon (AC) electrode in capacitive deionization (CDI) has attracted much attention due to its high electrical conductivity. However, self-agglomeration by π–π interactions between individual GE sheets required the use of high content to ensure an efficient conductive network in the electrode, which limited its practical application. This work proposed an approach to reduce the GE content in the fabrication of biomass-based activated carbon electrode for CDI application. The stacking effect of GE sheets is inhibited when GE sheets functionalize with oxygen groups via acid treatment under ultrasonic condition. This helps to reduce GE content to less than 2 wt% in the fabrication of CDI electrodes. The electrode fabricated using 2 wt% treated GE (T-GE) achieved the superior capacitance of 54 F/g, twice that of the pristine AC. The desalination process using as-prepared electrodes was evaluated by batch-mode CDI system with the initial NaCl solution of 2000 ppm and 3000 ppm at various applied voltages. The AC/T-GE 2 % electrode showed excellent performance with a desalination capacity greater than 10 mg/g, and reached an adsorption rate of 1.93 mg/g.min in both solutions under an applied voltage 1.2 V.