A polycatenated nickel(II) coordination polymer as a luminescence sensor for nitrofurantoin in aqueous medium

Liang Zhang, Weiwei Cheng
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引用次数: 0

Abstract

A Ni(II) complex, [Ni2(FDC)2(4,4′-BMIBP)2(H2O)2·3H2O] n (1) (4,4′-BMIBP = 4,4’-bis(2-methyl-imidazolyl)biphenyl, H2FDC = 2,5-furandicarboxylic acid) was hydrothermally synthesized and structurally characterized. Complex 1 possesses a polycatenated architecture based on an undulated (4,4)-sql layer. Complex 1 can be used for the selective detection of nitrofurantoin (NFT) in aqueous solutions. The luminescence quenching mechanism of complex 1 is attributed to the competitive absorption.
用作水介质中硝基呋喃妥因发光传感器的聚卡滕化镍(II)配位聚合物
通过水热法合成了镍(II)络合物[Ni2(FDC)2(4,4′-BMIBP)2(H2O)2-3H2O] n (1)(4,4′-BMIBP = 4,4'-bis(2-methyl-imidazolyl)biphenyl, H2FDC = 2,5-呋喃二甲酸),并对其进行了结构表征。络合物 1 具有基于波状 (4,4)-sql 层的多链烯结构。配合物 1 可用于水溶液中硝基呋喃妥因(NFT)的选择性检测。复合物 1 的发光淬灭机制归因于竞争性吸收。
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