{"title":"A polycatenated nickel(II) coordination polymer as a luminescence sensor for nitrofurantoin in aqueous medium","authors":"Liang Zhang, Weiwei Cheng","doi":"10.1515/znb-2023-0111","DOIUrl":null,"url":null,"abstract":"A Ni(II) complex, [Ni<jats:sub>2</jats:sub>(FDC)<jats:sub>2</jats:sub>(4,4′-BMIBP)<jats:sub>2</jats:sub>(H<jats:sub>2</jats:sub>O)<jats:sub>2</jats:sub>·3H<jats:sub>2</jats:sub>O]<jats:sub> <jats:italic>n</jats:italic> </jats:sub> (1) (4,4′-BMIBP = 4,4’-bis(2-methyl-imidazolyl)biphenyl, H<jats:sub>2</jats:sub>FDC = 2,5-furandicarboxylic acid) was hydrothermally synthesized and structurally characterized. Complex 1 possesses a polycatenated architecture based on an undulated (4,4)-sql layer. Complex 1 can be used for the selective detection of nitrofurantoin (NFT) in aqueous solutions. The luminescence quenching mechanism of complex 1 is attributed to the competitive absorption.","PeriodicalId":23831,"journal":{"name":"Zeitschrift für Naturforschung B","volume":"31 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift für Naturforschung B","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/znb-2023-0111","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
A Ni(II) complex, [Ni2(FDC)2(4,4′-BMIBP)2(H2O)2·3H2O]n (1) (4,4′-BMIBP = 4,4’-bis(2-methyl-imidazolyl)biphenyl, H2FDC = 2,5-furandicarboxylic acid) was hydrothermally synthesized and structurally characterized. Complex 1 possesses a polycatenated architecture based on an undulated (4,4)-sql layer. Complex 1 can be used for the selective detection of nitrofurantoin (NFT) in aqueous solutions. The luminescence quenching mechanism of complex 1 is attributed to the competitive absorption.
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