M. L. Busurina, V. A. Gorshkov, A. E. Sychev, O. D. Boyarchenko, I. D. Kovalev
{"title":"Polymorphism of High-Temperature Aluminothermic Synthesis Products in the Ni–Al–Co System","authors":"M. L. Busurina, V. A. Gorshkov, A. E. Sychev, O. D. Boyarchenko, I. D. Kovalev","doi":"10.1134/S0020168523100023","DOIUrl":null,"url":null,"abstract":"<p>Ni–Al–Co alloy with the composition 45 wt % Ni + 41 wt % Co + 14 wt % Al has been prepared for the first time by aluminothermic reaction. The phase composition of the synthesized alloy comprises a cubic (Ni,Co)<sub>3</sub>Al solid solution of cobalt in nickel aluminide (γ'-phase) and a tetragonal (Ni,Co)<sub>3</sub>Al phase. The formation of the tetragonal structure of (Ni,Co)<sub>3</sub>Al is due to a martensitic transformation of a supersaturated initial structure in grains of the cubic (Ni,Co)<sub>3</sub>Al phase. The intragranular microhardness of the synthesized alloy is 6500 MPa. The alloy has soft magnetic properties, with the highest magnetization of 27 emu/g in a magnetic field of 10 kOe.</p>","PeriodicalId":585,"journal":{"name":"Inorganic Materials","volume":"59 10","pages":"1069 - 1074"},"PeriodicalIF":0.9000,"publicationDate":"2024-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Materials","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S0020168523100023","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Ni–Al–Co alloy with the composition 45 wt % Ni + 41 wt % Co + 14 wt % Al has been prepared for the first time by aluminothermic reaction. The phase composition of the synthesized alloy comprises a cubic (Ni,Co)3Al solid solution of cobalt in nickel aluminide (γ'-phase) and a tetragonal (Ni,Co)3Al phase. The formation of the tetragonal structure of (Ni,Co)3Al is due to a martensitic transformation of a supersaturated initial structure in grains of the cubic (Ni,Co)3Al phase. The intragranular microhardness of the synthesized alloy is 6500 MPa. The alloy has soft magnetic properties, with the highest magnetization of 27 emu/g in a magnetic field of 10 kOe.
期刊介绍:
Inorganic Materials is a journal that publishes reviews and original articles devoted to chemistry, physics, and applications of various inorganic materials including high-purity substances and materials. The journal discusses phase equilibria, including P–T–X diagrams, and the fundamentals of inorganic materials science, which determines preparatory conditions for compounds of various compositions with specified deviations from stoichiometry. Inorganic Materials is a multidisciplinary journal covering all classes of inorganic materials. The journal welcomes manuscripts from all countries in the English or Russian language.