Phase Composition and Physicomechanical Properties of β-Sialons Prepared Using NaF as a Sintering Aid

IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY
N. S. Akhmadullina, V. P. Sirotinkin, K. A. Kim, A. S. Lysenkov, M. G. Frolova, S. V. Fedorov, N. A. Ovsyannikov, S. N. Ivicheva, Yu. F. Kargin
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Abstract

We have studied the effect of sodium fluoride as a sintering aid for β-sialons on the phase composition and physicomechanical properties of Si5AlON7 and Si4Al2O2N6. Two-step high-temperature firing of the β-sialons in the presence of NaF under a nitrogen atmosphere has been shown to cause no significant changes in the phase composition of the materials. The density and microhardness of the materials prepared using 0.5 and 5.0 wt % NaF are lower than those of the materials prepared without sintering aids, but the bending strength is higher by up to 14.3% in the case of Si5AlON7 prepared using 0.5 wt % NaF and by 4.9% in the case of Si4Al2O2N6 prepared using 5.0 wt % NaF.

Abstract Image

Abstract Image

用 NaF 作为烧结助剂制备的 β-硅胶的相组成和物理力学性能
摘要--我们研究了氟化钠作为β-硅烷基烧结助剂对 Si5AlON7 和 Si4Al2O2N6 的相组成和物理机械性能的影响。在氮气环境下,在 NaF 的存在下对 β-硅胶进行两步高温烧结,结果表明不会导致材料的相组成发生显著变化。使用 0.5 和 5.0 wt % NaF 制备的材料的密度和显微硬度低于不使用烧结助剂制备的材料,但使用 0.5 wt % NaF 制备的 Si5AlON7 的弯曲强度提高了 14.3%,使用 5.0 wt % NaF 制备的 Si4Al2O2N6 的弯曲强度提高了 4.9%。
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来源期刊
Inorganic Materials
Inorganic Materials 工程技术-材料科学:综合
CiteScore
1.40
自引率
25.00%
发文量
80
审稿时长
3-6 weeks
期刊介绍: Inorganic Materials is a journal that publishes reviews and original articles devoted to chemistry, physics, and applications of various inorganic materials including high-purity substances and materials. The journal discusses phase equilibria, including P–T–X diagrams, and the fundamentals of inorganic materials science, which determines preparatory conditions for compounds of various compositions with specified deviations from stoichiometry. Inorganic Materials is a multidisciplinary journal covering all classes of inorganic materials. The journal welcomes manuscripts from all countries in the English or Russian language.
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