Shiyu Wan , Peng Lu , Dongyan Xu , Valentin Valtchev
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引用次数: 0
Abstract
In the present study, siliceous self-pillared pentasil (SPP) zeolite with regular mesopores was synthesized and used as a support for anchoring bimetallic PdAg clusters through a facile impregnation-reduction method. The as-prepared PdAg/SPP catalysts with different Pd/Ag ratios were demonstrated to catalyze formic acid dehydrogenation for hydrogen production. XRD results confirmed the formation of PdAg alloy on the surface of SPP zeolite. The Pd7Ag3/SPP catalyst showed high activity at 80 °C with an initial turn-over frequency (TOF) of 1263.6 h−1, proving the strategy using hierarchical SPP zeolite as carrier is advantageous over bulky zeolites for making highly active formic acid dehydrogenation catalysts.
期刊介绍：
Catalysis Communications aims to provide rapid publication of significant, novel, and timely research results homogeneous, heterogeneous, and enzymatic catalysis.
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