I. S. Sipatov, O. A. Korolev, E. V. Ignatieva, L. A. Marshuk, B. R. Gelchinskiy, A. A. Rempel
{"title":"Mechanical Properties of High Entropy Alloys Based on Rare Earth Elements with Yttrium and Scandium","authors":"I. S. Sipatov, O. A. Korolev, E. V. Ignatieva, L. A. Marshuk, B. R. Gelchinskiy, A. A. Rempel","doi":"10.1134/s0031918x23601919","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>The paper reports the research outcomes on the structural and chemical composition of the equiatomic GdTbDyHoSc and GdTbDyHoY high-entropy alloys, which are potential materials for magnetic cold generators. The solidus and liquidus temperatures of the alloys were determined using differential scanning calorimetry. Based on these findings, an experimental mode of thermal cyclic treatment was selected. No signs of alloy destruction were observed after five test cycles for thermal resistance under exposure at a temperature of 1073 K (~0.6 of the melting point) for 15 minutes followed by quenching in room-temperature water. The applied heat treatment resulted in an increase in the hardness of alloys by 2–3 times and a decrease in wear resistance by 4–40 times depending on the alloy composition and the number of heat treatment cycles. Significant changes in the properties of alloys are associated with the formation of oxides, including REM<sub>2</sub>О<sub>3</sub>, not only on the surface but also within their volume, which is due to the high chemical activity of rare-earth metals. The data presented in this study will be beneficial in the development of thermal and thermomechanical treatment methods for studied alloys.</p>","PeriodicalId":20180,"journal":{"name":"Physics of Metals and Metallography","volume":"267 1","pages":""},"PeriodicalIF":1.1000,"publicationDate":"2024-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physics of Metals and Metallography","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1134/s0031918x23601919","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
引用次数: 0
Abstract
The paper reports the research outcomes on the structural and chemical composition of the equiatomic GdTbDyHoSc and GdTbDyHoY high-entropy alloys, which are potential materials for magnetic cold generators. The solidus and liquidus temperatures of the alloys were determined using differential scanning calorimetry. Based on these findings, an experimental mode of thermal cyclic treatment was selected. No signs of alloy destruction were observed after five test cycles for thermal resistance under exposure at a temperature of 1073 K (~0.6 of the melting point) for 15 minutes followed by quenching in room-temperature water. The applied heat treatment resulted in an increase in the hardness of alloys by 2–3 times and a decrease in wear resistance by 4–40 times depending on the alloy composition and the number of heat treatment cycles. Significant changes in the properties of alloys are associated with the formation of oxides, including REM2О3, not only on the surface but also within their volume, which is due to the high chemical activity of rare-earth metals. The data presented in this study will be beneficial in the development of thermal and thermomechanical treatment methods for studied alloys.
期刊介绍：
The Physics of Metals and Metallography (Fizika metallov i metallovedenie) was founded in 1955 by the USSR Academy of Sciences. Its scientific profile involves the theory of metals and metal alloys, their electrical and magnetic properties, as well as their structure, phase transformations, and principal mechanical properties. The journal also publishes scientific reviews and papers written by experts involved in fundamental, application, and technological studies. The annual volume of publications amounts to some 250 papers submitted from 100 leading national scientific institutions.
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