Silver fused multifunctional CeIn2O5 nanoparticle: Photocatalytic, antibacterial and electrochemical sensor studies

Shivaswamy M B , Karthikdev P , Madhukar B S , Hemanth B S , Deviprasad M J , Kavya R , Sangamesha M A , Anand A P , Spoorthy H P , Nagendra Prasad H S
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Abstract

The current work reveals the creation of Ag: CeIn2O5 (ACI NPs) metallic oxide nanoparticles using solution combustion for antibacterial research, photocatalytic degradation of a malachite green and electrochemical quantification of substances. Different analytical techniques were used to determine the chemical, physical and structural aspects of ACI NPs. The prepared ACI NPs is subjected to UV–Vis spectroscopy to evaluate the absorption and energy band gap, which was found to be 349 ​nm (λmax) and 3.5 ​eV respectively. Malachite green (5 ​ppm) elimination in the presence of UV–visible light was examined by utilising ACI NPs as a photo-catalyst. Due to improved charge separation and quick electron mobility with in the nanoparticles, the ACI NPs demonstrated a superior photocatalytic degradation efficiency (94.4%). Additionally, a functional electrode containing ACI NPs was developed by modifying a glassy carbon electrode (GCE) with ACI NPs. According to electrochemical studies to quantify H2O2, which shows the linearity in peak current with concentration ranges from 2.5 to 15 ​mM. The antibacterial property of the prepared nanoparticles was characterised by comparing with the standard antibiotic streptomycin at 10 μg/disc in a dose-dependent manner (20, 25, 30, 35, 40, & 45 ​μg/mL) which exhibits the zone of inhibition (ZOI) of 19.2–32.25 ​± ​0.08 ​mm, against methicillin resistant staphylococcus aureus (MRSA) in a dose-dependent method. As a result, it was established that the ACI NPs acts effectively as a multifunctional material and could be scaled up for the detection of H2O2, degradation of malachite green and possess antibacterial activity against MRSA.

Abstract Image

银融合多功能 CeIn2O5 纳米粒子:光催化、抗菌和电化学传感器研究
目前的研究揭示了利用溶液燃烧法制造 Ag:CeIn2O5 (ACI NPs) 金属氧化物纳米粒子,用于抗菌研究、光催化降解孔雀石绿和电化学物质定量。使用不同的分析技术来确定 ACI NPs 的化学、物理和结构方面。对制备的 ACI NPs 进行紫外可见光谱分析,以评估其吸收和能带间隙,结果发现其吸收和能带间隙分别为 349 nm (λmax) 和 3.5 eV。利用 ACI NPs 作为光催化剂,考察了孔雀石绿(5 ppm)在紫外可见光下的消除情况。由于纳米粒子中的电荷分离得到了改善,电子迁移速度加快,ACI NPs 显示出卓越的光催化降解效率(94.4%)。此外,通过用 ACI NPs 对玻璃碳电极(GCE)进行改性,开发出了含有 ACI NPs 的功能电极。通过电化学研究对 H2O2 进行定量,结果表明其峰值电流在 2.5 至 15 mM 的浓度范围内呈线性关系。通过与标准抗生素链霉素(10 μg/disc, 20, 25, 30, 35, 40, & 45 μg/mL)进行剂量依赖性(20、25、30、35、40、& 45 μg/mL)比较,制备的纳米粒子的抗菌特性得到了表征,其对耐甲氧西林金黄色葡萄球菌(MRSA)的抑制区(ZOI)为 19.2-32.25 ± 0.08 mm。结果表明,ACI NPs 是一种有效的多功能材料,可放大用于检测 H2O2、降解孔雀石绿,并对 MRSA 具有抗菌活性。
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