Microstructure and Tribological Behavior of Plasma Sprayed (Ti,Cr)C-Ni Composite Coatings

Maryna Storozhenko, O. Umanskyi, Oleksiy Melnyk, O. Terentyev, Tatiana Chevychelova, V. Varchenko, O. Koval, V. Brazhevsky, O. Chernyshov
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Abstract

Thermally sprayed cermet coatings are widely used in many engineering applications to protect against wear and corrosion. In this study, three kinds of (Ti,Cr)C-based powders with 18, 25, 33 wt.% content of Ni binder were deposited onto stainless steel substrates by plasma spraying technique. The microstructure and dry sliding wear resistance of the (Ti,Cr)C-Ni coatings were investigated. The (Ti,Cr)C-Ni coatings have a heterogeneous structure composed of (Ti,Cr)C particles and Ni binder. Fracture and partial dissolution of the (Ti,Cr)C particles were found to occur during the plasma spray process. Among all the tested coatings, (Ti,Cr)C-33wt.%Ni coating exhibits lower wear rates and friction coefficients under all conditions. Worn surfaces of the coatings were analyzed using SEM to investigate the wear mechanism. With the increase in Ni content from 18 up to 33wt.%Ni wear mechanism of the (Ti,Cr)C-Ni coatings changes from abrasive to tribo-oxidation.
等离子喷涂(Ti,Cr)C-Ni 复合涂层的微观结构和摩擦学行为
热喷涂金属陶瓷涂层被广泛应用于许多工程领域,以防止磨损和腐蚀。本研究采用等离子喷涂技术在不锈钢基材上沉积了三种镍粘结剂含量分别为 18、25、33 wt.% 的(Ti,Cr)C 基粉末。研究了(Ti,Cr)C-Ni 涂层的微观结构和干滑动耐磨性。(Ti,Cr)C-Ni涂层具有由(Ti,Cr)C颗粒和镍粘结剂组成的异质结构。在等离子喷涂过程中,(Ti,Cr)C 颗粒发生了断裂和部分溶解。在所有测试涂层中,(Ti,Cr)C-33wt.%Ni 涂层在所有条件下都表现出较低的磨损率和摩擦系数。使用扫描电镜分析了涂层的磨损表面,以研究磨损机理。随着镍含量从 18% 增加到 33%,(Ti,Cr)C-Ni 涂层的磨损机理从磨蚀转变为三氧化反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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