Gadolinium concentration measurement with an atomic absorption spectrophotometer

Abstract

Because gadolinium (Gd) has the highest thermal neutron capture cross section, resulting in an 8 MeV gamma cascade upon capture, it has been proposed for dissolution in water Cherenkov detectors to achieve efficient neutron tagging capabilities. While metallic Gd is insoluble in water, several compounds are very easy to dissolve. Gadolinium sulfate, Gd2(SO4)3, has been thoroughly tested and proposed as the best candidate. Accurate measurement of its concentration, free of doubt from impurities in water, is crucial. An atomic absorption spectrophotometer (AAS) is a device that suits this purpose and is widely used to measure the concentration of many elements. In this study, we describe three different approaches to measure Gd sulfate concentrations in water using an AAS: doping samples with potassium and lanthanum, and employing tantalum and tungsten platforms.