V. O. Samoilov, Iu. I. Porukova, A. A. Kozhevnikov, V. A. Lavrentev, A. A. Porsin, M. I. Kniazeva
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引用次数: 0
Abstract
The present study investigates the regularities of synthesis of methyl glycerol ethers (MGEs) in direct intermolecular dehydration between glycerol and methanol over BEA-type zeolite. The following reaction conditions were varied during the study: temperature (140, 160, and 180°C), pressure (3.0, 5.0, and 7.0 MPa), volume hourly space velocity (0.5 and 1.0 h–1), and methanol to glycerol molar ratio (5 : 1 and 10 : 1). The compositions of the reaction mixtures prepared, as well as the isomeric compositions of the mono- and disubstituted glycerol ethers, were described. The material balances of the process were provided for each combination of operating conditions. The variations in the glycerol conversion, the yields of MGEs, the yield of dimethyl ether as a by-product, and the selectivity towards monomethyl glycerol ethers (relative to dimethyl ones) were investigated as functions of the reaction conditions.
期刊介绍：
Petroleum Chemistry (Neftekhimiya), founded in 1961, offers original papers on and reviews of theoretical and experimental studies concerned with current problems of petroleum chemistry and processing such as chemical composition of crude oils and natural gas liquids; petroleum refining (cracking, hydrocracking, and catalytic reforming); catalysts for petrochemical processes (hydrogenation, isomerization, oxidation, hydroformylation, etc.); activation and catalytic transformation of hydrocarbons and other components of petroleum, natural gas, and other complex organic mixtures; new petrochemicals including lubricants and additives; environmental problems; and information on scientific meetings relevant to these areas.
Petroleum Chemistry publishes articles on these topics from members of the scientific community of the former Soviet Union.
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