Geochemical and petrological studies of high sulfur coal and overburden from Makum coalfield (Northeast India) towards understanding and mitigation of acid mine drainage

IF 6.9 1区 工程技术 Q2 ENERGY & FUELS
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Abstract

Opencast coal mining produces trash of soil and rock containing various minerals, that are usually dumped nearby the abandoned sites which causes severe environmental concern including the production of acid mine drainage (AMD) through oxidation pyrite minerals. The current study entailed assessing the potential production of AMD from an opencast coal mining region in Northeast part of India. In order to have a comprehensive overview of the AMD problem in Makum coalfield, the physico-chemical, geochemical, and petrological characteristics of the coal and overburden (OB) samples collected from the Makum coalfield (Northeast India) were thoroughly investigated. The maceral compositions reveal that coal features all three groups of macerals (liptinite, vitrinite, and inertinite), with a high concentration of liptinite indicating the coal of perhydrous, thereby rendering it more reactive. Pyrite (FeS2) oxidation kinetics were studied by conducting the aqueous leaching experiments of coal and (OB) samples to interpret the chemical weathering under controlled laboratory conditions of various temperature and time periods, and to replicate the actual mine site leaching. Inductively coupled plasma-optical emission spectroscopy (ICP-OES) was operated to detect the disposal of some precarious elements from coal and OB samples to the leachates during our controlled leaching experiment. The Rare earth element (REE) enrichment in the samples shows the anthropogenic incorporation of the REE in the coal and OB. These experiments reveal the change in conductivity, acid producing tendency, total dissolved solid(TDS), total Iron(Fe) and dissolved Sulfate(SO42−) ions on progress of the leaching experiments. Moreover, the discharge of FeS2 via atmospheric oxidation in laboratory condition undergoes a significant growth with the rise of temperature of the reaction systems in the environment and follows pseudo first order kinetics. A bio-remediative strategies is also reported in this paper to mitigate AMD water by employing size-segregated powdered limestone and water hyacinth plant in an indigenously developed site-specific prototype station. Apart from neutralisation of AMD water, this eco-friendly AMD remediation strategy demonstrates a reduction in PHEs concentrations in the treated AMD water.

对马库姆煤田(印度东北部)的高硫煤和覆盖层进行地球化学和岩石学研究,以了解和缓解酸性矿井排水问题
摘要 露天开采煤炭会产生含有各种矿物质的土壤和岩石垃圾,这些垃圾通常被倾倒在废弃场地附近,造成严重的环境问题,包括黄铁矿氧化产生的酸性矿井排水(AMD)。当前的研究需要评估印度东北部露天煤矿开采区可能产生的酸性矿井排水。为了全面了解马库姆煤田的 AMD 问题,对从马库姆煤田(印度东北部)采集的煤炭和覆盖层(OB)样本的物理化学、地球化学和岩石学特征进行了深入研究。宏观成分显示,煤炭具有所有三组宏观矿物(锂辉石、玻璃石和惰性石),高浓度的锂辉石表明煤炭具有过水性,从而使其更具活性。黄铁矿(FeS2)氧化动力学研究通过对煤炭和(OB)样品进行水浸出实验来解释在不同温度和时间段的受控实验室条件下的化学风化,并复制实际矿区浸出情况。在受控浸出实验中,我们使用了电感耦合等离子体-光学发射光谱(ICP-OES)来检测煤炭和转炉样本中一些不稳定元素在浸出液中的弃置情况。样品中的稀土元素富集表明煤炭和转炉煤中人为加入了稀土元素。这些实验揭示了电导率、产酸倾向、总溶解固体(TDS)、总铁(Fe)和溶解硫酸根(SO42-)离子在浸出实验过程中的变化。此外,实验室条件下通过大气氧化法排放的 FeS2 随环境中反应体系温度的升高而显著增加,并遵循伪一阶动力学。本文还报告了一种生物补救策略,即在本地开发的特定地点原型站中采用粒度分隔的粉状石灰石和水葫芦植物来缓解 AMD 水。除了中和 AMD 水之外,这种生态友好型 AMD 治理策略还能降低经处理的 AMD 水中 PHEs 的浓度。
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来源期刊
CiteScore
11.40
自引率
8.40%
发文量
678
审稿时长
12 weeks
期刊介绍: The International Journal of Coal Science & Technology is a peer-reviewed open access journal that focuses on key topics of coal scientific research and mining development. It serves as a forum for scientists to present research findings and discuss challenging issues in the field. The journal covers a range of topics including coal geology, geochemistry, geophysics, mineralogy, and petrology. It also covers coal mining theory, technology, and engineering, as well as coal processing, utilization, and conversion. Additionally, the journal explores coal mining environment and reclamation, along with related aspects. The International Journal of Coal Science & Technology is published with China Coal Society, who also cover the publication costs. This means that authors do not need to pay an article-processing charge.
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