Electrosynthesis of Sugar Derivatives

IF 1.9 4区 化学 Q2 CHEMISTRY, ORGANIC
Cintia Santiago, Natividad Bejarano Rengel, Pablo Fernández, Agustin Ponzinibbio
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引用次数: 0

Abstract

: The last decades have witnessed significant advances in the synthesis of bioactive carbohydrates. As in all fields of organic synthesis, the search for more environmentally friendly alternative synthetic methods is a current and expanding concern. Consequently, electrochemical organic synthesis has emerged as an efficient and sustainable methodology. Herein, we present recent developments in the synthesis of glycosides and other carbohydrate derivatives using electrochemical methods. Diverse natural and synthetic O-, S-, and C-glycosides were obtained using new approaches for the electrochemical activation of sugar precursors. The reported derivatives exhibited wide structural diversity on both the sugar moiety and the aglycone, revealing the great potential of the electrochemical methods.
糖衍生物的电合成
:过去几十年来,生物活性碳水化合物的合成取得了重大进展。与有机合成的所有领域一样,寻找更环保的替代合成方法是当前日益受到关注的问题。因此,电化学有机合成已成为一种高效、可持续的方法。在此,我们将介绍利用电化学方法合成苷类和其他碳水化合物衍生物的最新进展。我们采用新方法对糖前体进行电化学活化,获得了多种天然和合成的 O-、S- 和 C-糖苷。所报道的衍生物在糖分子和苷元上都表现出广泛的结构多样性,揭示了电化学方法的巨大潜力。
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来源期刊
Mini-reviews in Organic Chemistry
Mini-reviews in Organic Chemistry 化学-有机化学
CiteScore
4.50
自引率
4.30%
发文量
116
审稿时长
>12 weeks
期刊介绍: Mini-Reviews in Organic Chemistry is a peer reviewed journal which publishes original reviews on all areas of organic chemistry including organic synthesis, bioorganic and medicinal chemistry, natural product chemistry, molecular recognition, and physical organic chemistry. The emphasis will be on publishing quality papers very rapidly, without any charges. The journal encourages submission of reviews on emerging fields of organic chemistry including: Bioorganic Chemistry Carbohydrate Chemistry Chemical Biology Chemical Process Research Computational Organic Chemistry Development of Synthetic Methodologies Functional Organic Materials Heterocyclic Chemistry Macromolecular Chemistry Natural Products Isolation And Synthesis New Synthetic Methodology Organic Reactions Organocatalysis Organometallic Chemistry Theoretical Organic Chemistry Polymer Chemistry Stereochemistry Structural Investigations Supramolecular Chemistry
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